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Product Details
Reaction |
Ligand for Pd-catalyzed cross-coupling. Useful ligand for Pd-catalyzed carbon-nitrogen and carbon-oxygen bond forming procedures. Ligand for Ni-catalyzed amination of aryl chlorides. Ligand for Pd-catalyzed conversion of aryl halides to aryl nitriles. Ligand for Ni-catalyzed Suzuki reactions. Ni-catalyzed hydroamination of 1,3-dienes. Pd-catalyzed hydrocarbonation and hydroamination of 3,3-dihexylcyclopropene. Pd-catalyzed γ-arylation of β,γ-unsaturated ketones. Ligand for Ru-catalyzed reduction of nitriles to primary amines. Ligand for Rh-catalyzed alkyne head-to-tail dimerization. Ligand for Rh-catalyzed cross-coupling Ligand for Rh-catalyzed olefin isomerization Ligand for Ni or Rh-catalyzed borylation Ligand for regioselective Pd-catalyzed hydrophosphinylation of terminal alkynes to form branched alkenes. |
Chemical Properties |
1,1'-Bis(diphenylphosphino)ferrocene is deep yellow crystalline powder |
Uses |
suzuki reaction. 1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. |
General Description |
Novel functionalized furan derivatives were prepared via Pd-phosphine sequential C-C and C-O bond formation. 1,1′-bis(diphenylphosphino)ferrocene (dppf) finds the increasing use in coordination chemistry, catalysis, and materials science as stable, redox-active, conformationally flexible diphosphine ligand. |
Purification Methods |
Wash it with distilled H2O and dry it in a vacuum. Dissolve it in ca 5 parts of hot dioxane and cool to give orange crystals m 181-183o. Recrystallisation from *C6H6/heptane (1:2) gives a product with m 183-184o. [Bishop et al. J Organomet Chem 27 241 1971.] |
(1,1'-Ferrocenediyl)phenyl-phosphine and...
When bisphosphine is taken in a significant excess, the cyclic core rearranges to the linear complex featuring chelating and bridging 1,1′-bis(phosphino)ferrocenes and κ1 coordinated pyrazolate anion. The electronic transitions observed in these complexes are qualitatively described by TD-DFT calculations.
A series of five new heteroleptic 1,1′-bis (diphenylphosphino)ferrocene (dppf) appended nickel (II) dithiolates namely, [Ni (dppf)(benzylcyanidedithiolate)] (Bz-Ni), [Ni (dppf)(2-cyanobenzylcyanidedithiolate)] (CN-Ph-Ni) and [Ni (dppf)(pyridine-2-cyanidedithiolate)] (2-Py-Ni), [Ni (dppf)(pyridine-3-cyanidedithiolate)] (3-Py-Ni), Ni (dppf)(thiophene-2-cyanidedithiolate)] (Th-Ni) have been prepared and characterized using spectroscopic techniques and in one case by single-crystal X-ray diffraction analysis for CN-Ph-Ni.
[Fe(η5-C5H4P(OPh)2)2]
1,1'-bis-(diphenylphosphino)ferrocene
Conditions | Yield |
---|---|
With tributylphosphine; iodine; In tetrahydrofuran; acetonitrile; at 20 ℃; for 0.166667h; Inert atmosphere;
|
94% |
bis(2-(diphenylphosphoryl)cyclopenta-2,4-dien-1-yl)iron
1,1'-bis-(diphenylphosphino)ferrocene
Conditions | Yield |
---|---|
With Bis(p-nitrophenyl) phosphate; 1,3-diphenyl-disiloxane; In ethyl acetate; at 23 ℃; for 48h; chemoselective reaction; Sealed tube;
|
83% |
With bis(2-chlorophenyl)borinic acid; phenylsilane; In toluene; at 80 ℃; for 18h; Inert atmosphere;
|
71% |
With [AlH3(triethylamine)]; In hexane; at 20 ℃; for 0.166667h; Inert atmosphere; Schlenk technique;
|
93 %Chromat. |
1,1'-dilithioferrocene
phenylthiodiphenylphosphine
phenyllithium
chloro-diphenylphosphine
3-ethoxypropanal
ethoxypropionaldehyde
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride
palladium
CAS:11070-44-3
Molecular Formula:C<sub>9</sub>H<sub>10</sub>O<sub>3</sub>
Molecular Weight:166.17
CAS:13716-12-6
Molecular Formula:C<sub>12</sub>H<sub>27</sub>P
Molecular Weight:202.32
CAS:19845-69-3
CAS:166330-10-5
Molecular Formula:C36H28OP2
Molecular Weight:538.6