12150-46-8

Product Name1,1'-Bis(diphenylphosphino)ferrocene
Purity99%

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CasNo： 12150-46-8
Purity： 99%

High Purity 1,1'-Bis(diphenylphosphino)ferrocene 12150-46-8 Global supply

Molecular Formula:C34H28FeP2
Molecular Weight:556.407
Appearance/Colour:deep yellow crystalline powder
Melting Point:181-182 °C (dec.)(lit.)
Boiling Point:363.8oC at 760mmHg
Flash Point:182.8oC
PSA：27.18000
LogP:6.38890

1,1'-Bis(diphenylphosphino)ferrocene(Cas 12150-46-8) Usage

Description	1,1′-Bis(diphenylphosphino)ferrocene (dppf), a diphosphine ligand utilized prominently in homogeneous catalysis, boasts a ferrocene backbone and serves as a pivotal component in various transition metal-catalyzed reactions. Commonly abbreviated as dppf, this compound exhibits deep yellow crystalline properties.
Chemical Properties	1,1'-Bis(diphenylphosphino)ferrocene is deep yellow crystalline powder
Uses	1,1'-Bis(diphenylphosphino)ferrocene (dppf) serves as a crucial ligand in homogeneous catalysis, particularly in palladium-catalyzed coupling reactions, but its utility extends to various other transition metals such as rhodium and nickel. It facilitates a broad spectrum of catalytic transformations including cross-coupling reactions, carbon-nitrogen and carbon-oxygen bond formations, Suzuki reactions, hydroaminations, γ-arylation of ketones, and regioselective hydrophosphinylation of terminal alkynes, highlighting its versatility in modern synthetic methodologies. As a stable, redox-active ligand, dppf finds increasing application in coordination chemistry, catalysis, and materials science, underscoring its significance in diverse chemical transformations and materials synthesis.

12150-46-8 Relevant articles

FERROCENOPHANES WITH PHOSPHORUS AND ARSENIC AS THE BRIDGING ATOMS: SYNTHESIS AND SOME REACTIONS. A NEW ROUTE TO FERROCENYLLITHIUM REAGENTS

Seyferth, Dietmar,Withers, Howard P.

, p. C1 - C5 (1980)

(1,1'-Ferrocenediyl)phenyl-phosphine and...

Heterobimetallic Silver(I) and Copper(I) pyrazolates supported with 1,1′-bis(diphenylphosphino)ferrocene

Aleksei A. Titov , Alexander F. Smol'yakov , Oleg A. Filippov

Journal of Organometallic Chemistry Volume 942, 14 June 2021, 121813

When bisphosphine is taken in a significant excess, the cyclic core rearranges to the linear complex featuring chelating and bridging 1,1′-bis(phosphino)ferrocenes and κ1 coordinated pyrazolate anion. The electronic transitions observed in these complexes are qualitatively described by TD-DFT calculations.

Effect of different aromatic groups on photovoltaic performance of 1,1′-bis (diphenylphosphino)ferrocene functionalized Ni (II) dithiolates as sensitizers in dye sensitized solar cells

Amita Singh, Archisman Dutta, Devyani Srivastava, Gabriele Kociok-Köhn, Ratna Chauhan, Suresh W. Gosavi, Abhinav Kumar, Mohd. Muddassir

Applied Organometallic Chemistry, Volume35, Issue11 November 2021 e6402

A series of five new heteroleptic 1,1′-bis (diphenylphosphino)ferrocene (dppf) appended nickel (II) dithiolates namely, [Ni (dppf)(benzylcyanidedithiolate)] (Bz-Ni), [Ni (dppf)(2-cyanobenzylcyanidedithiolate)] (CN-Ph-Ni) and [Ni (dppf)(pyridine-2-cyanidedithiolate)] (2-Py-Ni), [Ni (dppf)(pyridine-3-cyanidedithiolate)] (3-Py-Ni), Ni (dppf)(thiophene-2-cyanidedithiolate)] (Th-Ni) have been prepared and characterized using spectroscopic techniques and in one case by single-crystal X-ray diffraction analysis for CN-Ph-Ni.