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Product Details
| Description |
(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE), a white to off-white crystalline powder or crystals, functions as a versatile ligand in various catalytic reactions, particularly in palladium-catalyzed transformations. |
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Chemical Properties |
White to off-white crystalline powder or crystals |
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Uses |
(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) plays a pivotal role as a ligand in various catalytic reactions, especially in palladium-catalyzed transformations. Its applications range from the formation of diaryl amines to C3 benzylation of indoles and monoallylation of ammonia. This compound is crucial in processes such as the palladium-catalyzed aerobic oxidation coupling of acyl chlorides with arylboronic acids, carbonylation of aryl iodides, direct C-H arylation of benzothiodiazoles, stereo-retentive azacyclization of propargylic carbonates, and palladium-catalyzed benzyne trimerization, showcasing its versatility in synthetic methodologies. Additionally, it serves as a ligand for ruthenium-catalyzed greener amine synthesis, exemplifying its role in sustainable catalysis by facilitating the transformation of amines and alcohols into amines. |
InChI:InChI=1/C36H28OP2/c1-5-17-29(18-6-1)38(30-19-7-2-8-20-30)35-27-15-13-25-33(35)37-34-26-14-16-28-36(34)39(31-21-9-3-10-22-31)32-23-11-4-12-24-32/h1-28H
Three new lanthanide heterocyclic β-diketonate complexes having the general formula Ln(PBI)3(DPEPO) [HPBI = 3-phenyl-4-benzoyl-5-isoxazolone, DPEPO = bis(2-(diphenylphosphino)phenyl) ether oxide and Ln3+ = Eu3+ (1), Tb3+ (2), and Gd3+ (3)] have been synthesized.
The controllable tuning of the excited s...
The pseudotetrahedral complexes [Cu(NN)(DPEphos)]BF4, where DPEphos = bis[2-(diphenylphosphino)phenyl]ether and NN = 1,10-phenanthroline (1), 2,9-dimethyl-1,10-phenanthroline (2), 2,9-di-n-butylphenanthroline (3), or two dimethylcyanamides (4), and NiCl2(DPEphos) (5) have been synthesized and structurally characterized by X-ray crystallography and their solution properties examined by use of a combination of cyclic voltammetry, NMR spectroscopy, and electronic absorption spectroscopy.
diphenylether
chloro-diphenylphosphine
bis[2-(diphenylphosphino)phenyl] ether oxidebis[2-(diphenylphosphino)phenyl] ether oxide
porphyrin
(O(C6H4P(C6H5)2)2NP(O)(OC6H5)2)
CAS:657408-07-6
Molecular Formula:C26H35O2P
Molecular Weight:410.5
CAS:12150-46-8
CAS:261733-18-0
