Your Location：Home >Products >Organic phosphines >Tert-butyl phosphines >13716-12-6
.jpg)
Product Details
|
Reaction |
Useful as a ligand in a variety of palladium-catalyzed C-N, C-O and C-C bond-forming reactions under mild conditions. |
|
Chemical Properties |
Colorless to light yellow liqui |
|
Uses |
Tri-tert-butylphosphine is used primarily in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions. Tri-tert-butylphosphine is an efficient promoter for the trifluoromethylation reactions of aldehydes, ketones, imides and imines. |
InChI:InChI=1/C12H27P/c1-10(2,3)13(11(4,5)6)12(7,8)9/h1-9H3
Metal-only Lewis pairs (MOLPs) based on ...
A variety of tertiary phosphine sulfides...
However, a GaP ALD process has not yet been reported using TEGa and safer tri-tert-butylphosphine (tri-TBP) since the tri-TBP needs a high temperature to be reactive on Si (1 0 0), …
tert-butylmagnesium chloride
phosphorus trichloride
tri-tert-butyl phosphine
| Conditions | Yield |
|---|---|
|
With lithium bromide; copper(l) iodide; In diethyl ether; hexane; at -20 - 20 ℃; for 4h;
|
88.3% |
tert-butylmagnesium chloride
tri-tert-butyl phosphine
| Conditions | Yield |
|---|---|
|
With boron trifluoride-tetrahydrofuran complex; phosphorus trichloride; In tetrahydrofuran; at -10 - 0 ℃; for 3h; Reagent/catalyst; Inert atmosphere;
|
94.3% |
|
With phosphorus trichloride;
|
tert-butylmagnesium chloride
di(tert-butyl)chlorophosphine
tert.-butyl lithium
Tri-tert-butylphosphantellurid
tricyclohexylphosphine
methyldi-t-butylphosphine
2-methylphenyl bromide
2-methylchlorobenzene
.jpg)
CAS:98327-87-8
Molecular Formula:C<sub>44</sub>H<sub>32</sub>P<sub>2</sub>
Molecular Weight:622.7
.jpg)
CAS:1001911-63-2
Molecular Formula:C<sub>18</sub> H<sub>14</sub> BNO<sub>2</sub>
Molecular Weight:287.1
.jpg)
CAS:85-43-8
Molecular Formula:C<sub>8</sub>H<sub>8</sub>O<sub>3</sub>
Molecular Weight:152.15
