Your Location：Home >Products >OLED intermediates >Boric acids >5122-94-1

5122-94-1

  • Product Name4-Biphenylboronic acid
  • Molecular FormulaC12H11BO2
  • Molecular Weight198.03
  • Purity99%
Inquiry

Product Details

Quick Details

  • CasNo： 5122-94-1
  • Molecular Formula： C12H11BO2
  • Purity： 99%

4-Biphenylboronic acid 5122-94-1 Powder In Medicine

  • Molecular Formula:C12H11BO2
  • Molecular Weight:198.029
  • Appearance/Colour:Solid 
  • Vapor Pressure:1.24E-06mmHg at 25°C 
  • Melting Point:232-245 °C(lit.) 
  • Refractive Index:1.61 
  • Boiling Point:385.504 °C at 760 mmHg 
  • PKA:8.61±0.10(Predicted) 
  • Flash Point:186.946 °C 
  • PSA：40.46000 
  • Density:1.184 g/cm3 
  • LogP:1.03340 

4-Biphenylboronic acid(Cas 5122-94-1) Usage

Chemical Properties

Solid

Uses

suzuki reaction: Suzuki coupling of 2-(4-bromophenyl)thiophene with phenylboronic acid and 4-biphenylboronic acid are used for the preparation of 4-(2-thieny)biphenyl and 4-(2-thienyl)-1,1':4,1''-biphenyl respectively. Coupling of two equivalents of 4-(2-thienyl)phenylboronic acid with 1,4-diiodobenzene gives 4,4''-bis(2-thienyl)-1,1':4,1''-terphenyl and with 2,5-diiodothiophene, 2,5-bis[4-(2-thienyl)-phenyl]-thiophene is obtained.

Isomeric SMILES: B(C1=CC=C(C=C1)C2=CC=CC=C2)(O)O  
InChIKey: XPEIJWZLPWNNOK-UHFFFAOYSA-N  
InChI: InChI=1S/C12H11BO2/c14-13(15)12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9,14-15H  

5122-94-1 Relevant articles

Emission enhancement by formation of aggregates in hybrid chromophoric surfactant amphiphile/silica nanocomposites

Bhongale, Chetan Jagdish,Hsu, Chain-Shu

, p. 1404 - 1408 (2006)

(Figure Presented) In best order: Nanoag...

Novel κ2-Nim,S- and κ4-C,Nim,(μ-S),(μ-S)-coordination of di-2-thienyl ketone thiosemicarbazone (dtktsc). Hydrogen evolution and catalytic properties of palladacyclic [Pd(κ4-C,Nim,(μ-S),(μ-S)-dtktsc-2H)]4

Bakir, Mohammed,Bohari Yamin, M.,Lawrence, Mark W.

, (2020)

The reaction between di-2-thienyl ketone...

Low glucose concentration estimation based on reaction with 4, 4'-biphenyl boronic acid using deep learning

Yiru Li Chi Gao Haonan Jing Bozhao Fan Qi Fan Bingliang Hu Xuebin Liu Quan Wang Yutao Feng

Highlights in Science, Engineering and Technology, 2, 312–321.

As designed, we applied the 4,4'-Biphenylboronic acid mediated method to amplify the weak Raman signal of glucose by testing the strong Raman signal of the reaction product ((…

5122-94-1 Process route

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
Conditions Yield
4-bromo-1,1'-biphenyl; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1.5h; Inert atmosphere;
With Trimethyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 4.5h;
With water; In tetrahydrofuran; hexane; ethyl acetate;
84%
4-bromo-1,1'-biphenyl; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 2.5h;
With Triisopropyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃;
76%
4-bromo-1,1'-biphenyl; With magnesium; In tetrahydrofuran; for 4h; Heating;
With Trimethyl borate; In tetrahydrofuran; at 0 - 20 ℃;
67%
4-bromo-1,1'-biphenyl; With n-butyllithium; In tetrahydrofuran; hexanes; at -80 ℃; Inert atmosphere;
With Trimethyl borate; In tetrahydrofuran; hexanes; at -80 - 20 ℃; Inert atmosphere;
With hydrogenchloride; In tetrahydrofuran; hexanes; water; at 20 ℃; Inert atmosphere;
64%
Multistep reaction; (i) Mg, (ii) B(OMe)3, (iii) H2SO4;
 
4-bromo-1,1'-biphenyl; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;
With Triisopropyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 6h;
 
4-bromo-1,1'-biphenyl; With magnesium; In tetrahydrofuran; at 50 ℃; for 2h;
With Trimethyl borate; In tetrahydrofuran; at -60 - 15 ℃; for 2h; Further stages.;
 
Multi-step reaction with 2 steps
1.1: n-BuLi / tetrahydrofuran / 0.42 h / -78 °C
1.2: tetrahydrofuran / -78 - 20 °C
2.1: aq. HCl / 3 h / pH 6 - 7
With hydrogenchloride; n-butyllithium; In tetrahydrofuran;
 
4-bromo-1,1'-biphenyl; With magnesium; In tetrahydrofuran;
With Trimethyl borate;
With hydrogenchloride; Further stages.;
 
4-bromo-1,1'-biphenyl; With n-butyllithium; In diethyl ether; hexane; toluene; at -64 ℃; for 2.5h;
With Trimethyl borate; In diethyl ether; hexane; toluene; at 20 ℃; for 12.25h;
With hydrogenchloride; water; In diethyl ether; hexane; toluene; at 0 - 10 ℃;
 
With tetrahydroxydiboron; 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); N-ethyl-N,N-diisopropylamine; triphenylphosphine; In ethanol; at 20 ℃; for 6h; Inert atmosphere; Sealed tube;
 
Multi-step reaction with 2 steps
1.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere
1.2: 12 h / -78 - 20 °C / Inert atmosphere
2.1: hydrogenchloride / tetrahydrofuran / 0.5 h / Inert atmosphere
With hydrogenchloride; n-butyllithium; In tetrahydrofuran;
 
Multi-step reaction with 2 steps
1.1: magnesium; lithium chloride / Inert atmosphere; Schlenk technique
1.2: Inert atmosphere; Schlenk technique
2.1: copper(I) iodide-lithium chloride / tetrahydrofuran / 20 °C / Schlenk technique; Inert atmosphere
With copper(I) iodide-lithium chloride; magnesium; lithium chloride; In tetrahydrofuran;
 
Triisopropyl borate
5419-55-6

Triisopropyl borate

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

Conditions
Conditions Yield
4-bromo-1,1'-biphenyl; With n-butyllithium; In diethyl ether; hexane; at -78 ℃; for 0.5h;
Triisopropyl borate; In diethyl ether; hexane; at -78 - 20 ℃;
74%
With n-butyllithium; In tetrahydrofuran;
1.53 g (90%)

5122-94-1 Upstream products

  • 688-74-4
    688-74-4

    boric acid tributyl ester

  • 3315-91-1
    3315-91-1

    4-biphenylylmagnesium bromide

  • 92-66-0
    92-66-0

    4-bromo-1,1'-biphenyl

  • 1591-31-7
    1591-31-7

    4-iodo-biphenyl

5122-94-1 Downstream products

  • 105123-35-1
    105123-35-1

    2,4,6-tris([1,1'-biphenyl]-4-yl)boroxine

  • 5123-05-7
    5123-05-7

    2-([1,1'-biphenyl]-4-yl)-5,5-dimethyl-1,3,2-dioxaborinane

  • 324-74-3
    324-74-3

    4-fluoro-biphenyl

  • 174575-41-8
    174575-41-8

    (2S,5S)-5-[4-Acetoxy-5-(diethoxy-phosphorylmethyl)-[1,1';4',1'']terphenyl-3-ylmethyl]-2-tert-butyl-3-methyl-4-oxo-imidazolidine-1-carboxylic acid tert-butyl ester

Relevant Products

Links:

Tel:0393-8910800Phone:0393-8910800

Copyright © 2009-2024 Puyang Huicheng Electronic Material Co., Ltd