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Product Details
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Chemical Properties |
White solid |
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Uses |
9-Phenanthracenylboronic acid (9-PBA) is used as an fluorescent analytical reagent in sensing systems for glucose-specific detection. |
Isomeric SMILES: B(C1=CC2=CC=CC=C2C3=CC=CC=C13)(O)O
InChIKey: JCDAUYWOHOLVMH-UHFFFAOYSA-N
InChI: InChI=1S/C14H11BO2/c16-15(17)14-9-10-5-1-2-6-11(10)12-7-3-4-8-13(12)14/h1-9,16-17H
Recently, interest of polymer light-emit...
The present invention relates to aromati...
Furthermore, 9-phenanthracenylboronic acid could also undergo this selenylation with a … acid bearing o-Me (26) and m-Me (27) groups. Simultaneously, disubstituted arylboronic acid …
Trimethyl borate
9-bromophenanthrene
9-phenanthrenylboronic acid
| Conditions | Yield |
|---|---|
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9-bromophenanthrene; With n-butyllithium; In tetrahydrofuran; at -78 - 0 ℃; for 1h; Inert atmosphere;
Trimethyl borate; In tetrahydrofuran; at -78 - 20 ℃; for 12h; Inert atmosphere;
With hydrogenchloride; In tetrahydrofuran; water; for 0.5h; Inert atmosphere;
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82% |
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With n-butyllithium; In tetrahydrofuran; at -78 - 20 ℃; for 13.5h; Inert atmosphere;
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81% |
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9-bromophenanthrene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h; Inert atmosphere;
Trimethyl borate; In tetrahydrofuran; at 20 ℃; for 12h; Inert atmosphere;
With hydrogenchloride; water; In tetrahydrofuran; at 0 ℃; Inert atmosphere;
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81.1% |
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9-bromophenanthrene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h; Inert atmosphere;
Trimethyl borate; In tetrahydrofuran; at 20 ℃; for 12h; Inert atmosphere;
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81% |
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9-bromophenanthrene; With n-butyllithium; In tetrahydrofuran; at -76 ℃; for 0.166667h; Inert atmosphere;
Trimethyl borate; With hydrogenchloride; In tetrahydrofuran; water; at 20 ℃; for 1h; Inert atmosphere;
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42% |
Triisopropyl borate
9-bromophenanthrene
9-phenanthrenylboronic acid
| Conditions | Yield |
|---|---|
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Triisopropyl borate; 9-bromophenanthrene; With n-butyllithium; In tetrahydrofuran; hexanes; at -78 ℃; for 1h;
With hydrogenchloride; water; In tetrahydrofuran; hexanes; at -20 - 18 ℃; for 1h;
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89% |
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With n-butyllithium; In tetrahydrofuran; at -100 ℃; for 2h; Inert atmosphere;
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70% |
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9-bromophenanthrene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h; Inert atmosphere;
Triisopropyl borate; In tetrahydrofuran; for 1h;
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55% |
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9-bromophenanthrene; With n-butyllithium; In tetrahydrofuran; ethanol; at -78 - 20 ℃; for 2h; Inert atmosphere;
Triisopropyl borate; In tetrahydrofuran; ethanol; at -78 ℃; for 1h;
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36 g |
boric acid tributyl ester
Triisopropyl borate
9-bromophenanthrene
Trimethyl borate
2-(9-phenanthryl)-5-methoxybenzaldehyde
1-[1-{2-(1-naphthyl)-5-methoxyphenyl}]-2-methoxyethene
9-(2-(epoxyethyl)-4-methoxyphenyl)phenanthrene
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CAS:1001911-63-2
Molecular Formula:C<sub>18</sub> H<sub>14</sub> BNO<sub>2</sub>
Molecular Weight:287.1
CAS:1184301-61-8
