68572-87-2

  • Product Name9-Phenanthracenylboronic acid
  • Molecular FormulaC14H11BO2
  • Molecular Weight222.05
  • Purity99%
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Product Details

Quick Details

  • CasNo: 68572-87-2
  • Molecular Formula: C14H11BO2
  • Purity: 99%

9-Phenanthracenylboronic acid 68572-87-2 In Bulk Supply with Factory Price

  • Molecular Formula:C14H11BO2
  • Molecular Weight:222.051
  • Vapor Pressure:0mmHg at 25°C 
  • Melting Point:165-170 °C 
  • Refractive Index:1.71 
  • Boiling Point:479.505 °C at 760 mmHg 
  • PKA:8.53±0.30(Predicted) 
  • Flash Point:243.796 °C 
  • PSA:40.46000 
  • Density:1.268 g/cm3 
  • LogP:1.67280 

9-Phenanthracenylboronic acid(Cas 68572-87-2) Usage

Chemical Properties

White solid

Description 9-Phenanthracenylboronic acid (9-PBA) is used as an fluorescent analytical reagent in sensing systems for glucose-specific detection.

Uses

Reactant involved in the synthesis of:
Large polycyclic aromatic hydrocarbons (PAHs)
Electron rich benzo[g,h,i]perylenes
FLAP protein inhibitors as antiinflammatory agents
Aminoisoquinolinones as PARP-2 selective inhibitors

Isomeric SMILES: B(C1=CC2=CC=CC=C2C3=CC=CC=C13)(O)O  
InChIKey: JCDAUYWOHOLVMH-UHFFFAOYSA-N  
InChI: InChI=1S/C14H11BO2/c16-15(17)14-9-10-5-1-2-6-11(10)12-7-3-4-8-13(12)14/h1-9,16-17H  

68572-87-2 Relevant articles

Synthesis and luminescent properties of poly(9-(3-Vinyl-phenyl)-phenanthrene)

Yang, Garam,Lee, Hayoon,Lee, Suji,Jung, Hyocheol,Shin, Hwangyu,Lee, Jaehyun,Park., Jongwook

, p. 1748 - 1751 (2016)

Recently, interest of polymer light-emit...

Ligand Steric Effects of α-Diimine Nickel(II) and Palladium(II) Complexes in the Suzuki–Miyaura Cross-Coupling Reaction

Md Muktadir Talukder, John Michael O. Cue, Justin T. Miller, Prabhath L. Gamage, Amina Aslam, Gregory T. McCandless, Michael C. Biewer, and Mihaela C. Stefan*

ACS Omega 2020, 5, 37, 24018–24032

To evaluate the ligand steric effects, including the bite angle in the reaction outcomes, the structural variation of the complexes was achieved by incorporating iminopyridine- and acenaphthene-based ligands. Moreover, the impact of substrate bulkiness was investigated by reacting various aryl bromides with phenylboronic acid, 2-naphthylboronic acid, and 9-phenanthracenylboronic acid. Yields were the best with the dinuclear complex, being nearly quantitative (93–99%), followed by the mononuclear complexes, giving yields of 78–98%. Consequently, α-diimine-based ligands have the potential to deliver Ni-based systems as sustainable catalysts in SMC.

Electrochemical Mn-promoted radical selenylation of boronic acids with diselenide reagents

Ziyue Chen, Yuan Wang, Chenjian Hu, Daoxin Wang, Peilin Lei, Hong Yi*, Yong Yuan*, and Aiwen Lei*

Org. Lett. 2022, 24, 18, 3307–3312

Furthermore, 9-phenanthracenylboronic acid could also undergo this selenylation with a … acid bearing o-Me (26) and m-Me (27) groups. Simultaneously, disubstituted arylboronic acid …

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