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Product Details
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Chemical Properties |
Class white powder |
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Uses |
suzuki reaction |
InChI:InChI=1/C18H14BNO2/c21-19(22)13-9-11-14(12-10-13)20-17-7-3-1-5-15(17)16-6-2-4-8-18(16)20/h1-12,21-22H
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Conjugated microporous polymers (CMPs), ...
A deep blue emitting compound 9-(4′-(1,4...
Single layer structure is an ideal way t...
Inexpensive materials made of abundant n...
The invention relates to a preparation m...
The present invention provides a compoun...
The present invention relates to novel h...
In this work, we designed and synthesize...
Trimethyl borate
N-(4-bromophenyl)carbazole
4-(carbazol-9-yl)phenylboronic acid
| Conditions | Yield |
|---|---|
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N-(4-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - -65 ℃; for 1.5h; Inert atmosphere;
Trimethyl borate; In tetrahydrofuran; hexane; at -65 - 20 ℃; Inert atmosphere;
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85% |
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N-(4-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - -70 ℃; for 1.5h; Inert atmosphere;
Trimethyl borate; In tetrahydrofuran; hexane; at -70 - 20 ℃; Inert atmosphere;
With water;
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85% |
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With n-BuLi; HCl; In tetrahydrofuran; N2; n-BuLi 916 mmol) added to THF soln. of ligand (10 mmol) at -78°C, mixt. stirred for 1 h, B(OMe)3 (30 mmol) added, mixt. stirred for 2h, warmed to 0°C; 2 M HCl added, mixt. stirred for 3 h, extd. (ether), evapd.;
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80% |
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N-(4-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h;
Trimethyl borate; In tetrahydrofuran; at 20 ℃;
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80% |
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N-(4-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; hexane; at -70 ℃; for 1h; Inert atmosphere;
Trimethyl borate; In tetrahydrofuran; hexane; at 20 ℃; for 12h; Inert atmosphere;
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75.3% |
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N-(4-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;
Trimethyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃;
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70% |
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N-(4-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 2h;
Trimethyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 13h;
With hydrogenchloride; water; In tetrahydrofuran; hexane; at 20 ℃; for 1h;
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66% |
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N-(4-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h; Inert atmosphere;
Trimethyl borate; In tetrahydrofuran; Inert atmosphere;
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66.5% |
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N-(4-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 2h;
Trimethyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 25h;
With hydrogenchloride; water; In tetrahydrofuran; hexane; at 20 ℃; for 1h;
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65.9% |
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With hydrogenchloride; n-butyllithium; sodium chloride; In tetrahydrofuran;
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65.9% |
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With n-butyllithium; In not given; 4-(9H-carbazol-9-yl)phenyl-bromide treated with n-BuLi followed by trimethylborate;
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With CH3CH2CH2CH2Li; H3O(1+); In tetrahydrofuran; reaction of aryl bromide with butyllithium in THF at -78°C, treatment with boron compd. at -78°C, acidic hydrolysis;
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With n-butyllithium; In tetrahydrofuran; at -78 ℃;
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N-(4-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;
Trimethyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 12h;
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With n-butyllithium; In tetrahydrofuran; at -78 ℃; Inert atmosphere;
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N-(4-bromophenyl)carbazole; With n-butyllithium;
Trimethyl borate; In tetrahydrofuran; at -78 ℃; for 12h;
With hydrogenchloride; at 20 ℃;
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N-(4-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.166667h; Inert atmosphere;
Trimethyl borate; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;
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Triisopropyl borate
N-(4-bromophenyl)carbazole
4-(carbazol-9-yl)phenylboronic acid
| Conditions | Yield |
|---|---|
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N-(4-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;
Triisopropyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃;
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89% |
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N-(4-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;
Triisopropyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃;
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87% |
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N-(4-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; hexane; for 1h; Inert atmosphere;
Triisopropyl borate; In tetrahydrofuran; hexane; Inert atmosphere;
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86% |
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N-(4-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;
Triisopropyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; Inert atmosphere;
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85.91% |
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N-(4-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h; Inert atmosphere;
Triisopropyl borate; In tetrahydrofuran; at 20 ℃; for 12h; Inert atmosphere;
With hydrogenchloride; In tetrahydrofuran; water; for 0.166667h;
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67% |
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N-(4-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h; Inert atmosphere;
Triisopropyl borate; In tetrahydrofuran; at 20 ℃; for 12h; Inert atmosphere;
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67% |
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With n-butyllithium; In tetrahydrofuran; at -78 ℃; Inert atmosphere;
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N-(4-bromophenyl)carbazole
Trimethyl borate
1.4-dibromobenzene
9H-carbazole
4'-(carbazol-9-yl)-N-phenyl-[1,1'-biphenyl]-4-amine
C49H32N2
C56H38N2
C74H49N3
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CAS:1001911-63-2
Molecular Formula:C<sub>18</sub> H<sub>14</sub> BNO<sub>2</sub>
Molecular Weight:287.1
CAS:22034-43-1
