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184095-69-0

  • Product Name(R)-(-)-1-[(s)-2-(diphenylphosphino)ferrocenyl]ethyldi(3,5-dimethylphenyl)phosphine
  • Purity99%
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Product Details

Quick Details

  • CasNo： 184095-69-0
  • Purity： 99%

High Purity (R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE 184095-69-0 Powder

  • Molecular Formula:C40H40FeP2
  • Molecular Weight:638.552
  • Appearance/Colour:orange powder 
  • PSA：27.18000 
  • LogP:8.33990 

(R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE(Cas 184095-69-0) Usage

Reactions

Ligand for Rhodium-catalyzed asymmetric hydrogenation in the synthesis of tertiary carbinamide.

Chemical Properties

Orange powder

General Description

sold in collaboration with Solvias AG

InChI:InChI=1/C35H35P2.C5H5.Fe/c1-25-19-26(2)22-32(21-25)36(33-23-27(3)20-28(4)24-33)29(5)34-17-12-18-35(34)37(30-13-8-6-9-14-30)31-15-10-7-11-16-31;1-2-4-5-3-1;/h6-24,29H,1-5H3;1-5H;/t29-;;/m0../s1

184095-69-0 Relevant articles

Generation of Axially Chiral Fluoroallenes through a Copper-Catalyzed Enantioselective β-Fluoride Elimination

O'Connor, Thomas J.,Mai, Binh Khanh,Nafie, Jordan,Liu, Peng,Toste, F. Dean

supporting information, p. 13759 - 13768 (2021/09/07)

Herein we report the copper-catalyzed si...

Synthesis method of Josiphos chiral ferrocenyl phosphine ligands

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Paragraph 0007; 0059; 0060, (2017/05/27)

The invention discloses a synthesis meth...

184095-69-0 Process route

(diphenylphosphin)ferrocene
12098-17-8

(diphenylphosphin)ferrocene

vinyl bis(3,5-dimethylphenyl)phosphine

vinyl bis(3,5-dimethylphenyl)phosphine

(R)-(-)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylbis(3,5-dimethylphenyl)phosphine
184095-69-0

(R)-(-)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylbis(3,5-dimethylphenyl)phosphine

Conditions
Conditions Yield
With iron(III) chloride; D-Prolin; In dichloromethane; at 25 ℃; for 12h; Inert atmosphere;
95%
C<sub>40</sub>H<sub>40</sub>FeP<sub>2</sub>*2BH<sub>3</sub>

C40H40FeP2*2BH3

C<sub>40</sub>H<sub>40</sub>FeP<sub>2</sub>
184095-69-0

C40H40FeP2

Conditions
Conditions Yield
With 1,4-diaza-bicyclo[2.2.2]octane; In toluene; at 90 ℃; for 24h; Inert atmosphere; Schlenk technique;
 

184095-69-0 Upstream products

  • 12098-17-8
    12098-17-8

    (diphenylphosphin)ferrocene

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