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Product Details
Reaction |
Exceptional ligands for Pd-catalyzed amination and amidation of aryl sulfonates. ?Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling reaction and carbonyl enolate coupling. ?Ligand used for the chemoselective amination of aryl chlorides. ?Ligand used for the Pd-catalyzed borylation of aryl chlorides, for the formation of trifluoroborates. ?Ligand used for the Pd-catalyzed amination of vinyl halides and triflates. ?Ligand used for the Pd-catalyzed three-component synthesis of indoles. ?Ligand used for the Pt-catalyzed regioselective hydrosilylation of functionalized terminal arylalkynes. ?Ligand used for the Pd-catalyzed synthesis of carbazoles. ?Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling of aryl chloride and NHC-boranes. ?Ligand used for the direct arylation of picoline N-oxide. ?Ligand used for the Negishi coupling of 2-heterocyclic organozinc reagents. ?Catalyst for a phosphine-catalyzed Heine reaction. ?Ligand used for the palladium-catalyzed oxidative coupling of indoles and heteroarenes. ?Ligand used for the silver-catalyzed hydrogenation of aldehydes. ?Ligand used for the palladium-catalyzed cyanation of heterycyclic halides. |
Chemical Properties |
White crystalline powder |
Uses |
suzuki reaction |
General Description |
This product has been enhanced for catalytic efficiency. |
Isomeric SMILES: CC(C)C1=CC(=C(C(=C1)C(C)C)C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4)C(C)C
InChIKey: UGOMMVLRQDMAQQ-UHFFFAOYSA-N
InChI: InChI=1S/C33H49P/c1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28/h13-14,19-25,27-28H,7-12,15-18H2,1-6H3
Equilibrium constants were determined fo...
The invention discloses a method for syn...
The invention discloses a method for pre...
Br versus Cl: It is found that the use o...
2,4,6-triisopropyl-1-bromobenzene
chlorodicyclohexylphosphane
2,3-dibromobenzene
XPhos
Conditions | Yield |
---|---|
2,4,6-triisopropyl-1-bromobenzene; With n-butyllithium; In tetrahydrofuran; at 0 ℃; for 1h; Inert atmosphere;
2,3-dibromobenzene; In tetrahydrofuran; at 0 ℃; for 1h; Inert atmosphere;
chlorodicyclohexylphosphane; Further stages;
|
89% |
fluorobenzene
1,3,5-triisopropyl benzene
chlorodicyclohexylphosphane
XPhos
Conditions | Yield |
---|---|
fluorobenzene; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 2h; Inert atmosphere;
chlorodicyclohexylphosphane; In tetrahydrofuran; at 15 ℃; for 10h;
1,3,5-triisopropyl benzene; With n-butyllithium; potassium tert-butylate; In hexane; at 30 - 60 ℃; for 16h; Reagent/catalyst; Temperature;
|
93% |
2-bromo-1-chlorobenzene
2,4,6-triisopropyl-1-bromobenzene
chlorodicyclohexylphosphane
dicyclohexylbromophosphine
tert-butyl 2-(benzamido)-4-(1H-indol-1-yl)benzoate
tert-butyl 2-(benzamido)-4-(2-nitroanilino)benzoate
tert-butyl 2-(benzamido)-4-(1H-pyrrol-1-yl)benzoate
tert-butyl 2-(benzamido)-4-(4-phenylpiperidin-1-yl)benzoate
CAS:98327-87-8
Molecular Formula:C<sub>44</sub>H<sub>32</sub>P<sub>2</sub>
Molecular Weight:622.7
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