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Product Details
Chemical Properties
Yellow to light brown crystalline powder
The present invention relates to a novel metallocene compound represented by Chemical formula 1. According to the present invention, the metallocene compound can be used when an olefin-based polymer is produced and has excellent activity. The metallocene
A method for producing an anionized meso-form double-cross-linked ligand represented by formula (3), including: bringing a compound represented by formula (1) into contact with a compound represented by formula (2) at -25°C or less; and introducing an anionizing agent within 5 hours after the contact, wherein R1 to R10 are independently a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, or the like; A and A' are independently a cross-linking group containing an atom belonging to the 14th group of the periodic table; M and M' are independently an atom belonging to the 1st or the 2nd group of the periodic table.
The ansa-indene ligands {1-Me2Si(3-C9H 6R)2} [R = Me (1), nPr (2), nBu (3), and Bz (4)] were prepared by alkylation of the unsubstituted ansa-indene. These ligands were converted, by reaction with nBuLi, to the
A catalyst activator particularly adapted for use in the activation of metal complexes of metals of Group 3-10 for polymerization of ethylenically unsaturated polymerizable monomers, especially olefins, comprising a neutral (Lewis acid) or charge separated (cation/anion pair) comprising a boron ligand containing a fluorinated organic group containing from 10 to 1000 non-hydrogen atoms.
2-bromoindene
dimethylsilicon dichloride
bis(inden-1-yl)dimethylsilane
| Conditions | Yield |
|---|---|
|
With
magnesium;
In
tetrahydrofuran; ethylene dibromide;
Cooling with ice;
|
94% |
dimethylsilicon dichloride
1-indene
bis(inden-1-yl)dimethylsilane
| Conditions | Yield |
|---|---|
|
1-indene;
With
n-butyllithium;
dimethylsilicon dichloride;
|
|
|
In
tetrahydrofuran; hexane; toluene;
|
|
|
1-indene;
With
n-butyllithium;
In
diethyl ether; hexane;
at 0 - 20 ℃;
for 24h;
Inert atmosphere;
Schlenk technique;
dimethylsilicon dichloride;
In
diethyl ether; hexane;
at 20 ℃;
for 24h;
Schlenk technique;
Inert atmosphere;
|
indenyllithium
dimethylsilicon dichloride
1-indene
lithium indenide
meso-dimethylbis(1-indenyl)zirconocene dichloride
CAS:1450933-18-2
Molecular Formula:C25H15Br
Molecular Weight:395.3
CAS:1372778-66-9
Molecular Formula:C27H23N
Molecular Weight:361.5
CAS:102113-98-4
