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1462-03-9

  • Product Name1-Methylcyclopentanol
  • Molecular FormulaC6H12O
  • Molecular Weight100.16
  • Purity99%
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Product Details

Quick Details

  • CasNo： 1462-03-9
  • Molecular Formula： C6H12O
  • Purity： 99%

High Quality 1-Methyl cyclopentanol 1462-03-9 with Factory Price

  • Molecular Formula:C6H12O
  • Molecular Weight:100.161
  • Appearance/Colour:white crystalline low melting solid 
  • Vapor Pressure:3.03mmHg at 25°C 
  • Melting Point:36-37 °C(lit.) 
  • Refractive Index:1.473 
  • Boiling Point:137.1 °C at 760 mmHg 
  • PKA:15.38±0.20(Predicted) 
  • Flash Point:40.6 °C 
  • PSA：20.23000 
  • Density:0.961 g/cm3 
  • LogP:1.31140 

1462-03-9 Usage

1-Methylcyclopentanol is a very flammable and toxic irritant chemical.

Chemical Properties

white crystalline low melting solid

Synthesis Reference(s)

Tetrahedron Letters, 29, p. 6753, 1988 DOI: 10.1016/S0040-4039(00)82446-6

InChI:InChI=1/C6H12O/c1-6(7)4-2-3-5-6/h7H,2-5H2,1H3

1462-03-9 Relevant articles

Simultaneous observation of alkenyl carbenium ions and alkoxy species on HZSM-5 zeolite by adsorption of 1-methylcyclopentene and 1-methylcyclopentanol

S Yang, JN Kondo, K Domen

J. Phys. Chem. B 2001, 105, 33, 7878–7881

The adsorption and reaction of 1-methylcyclopentene (MCPE) and 1-methylcyclopentanol (MCPOH) on HZSM-5 were studied by in-situ FTIR spectroscopy at 150−295 K. For MCPE, …

Deciphering Reactivity and Selectivity Patterns in Aliphatic C-H Bond Oxygenation of Cyclopentane and Cyclohexane Derivatives

Martin, Teo,Galeotti, Marco,Salamone, Michela,Liu, Fengjiao,Yu, Yanmin,Duan, Meng,Houk,Bietti, Massimo

supporting information, p. 9925 - 9937 (2021/06/30)

A kinetic, product, and computational study on the reactions of the cumyloxyl radical with monosubstituted cyclopentanes and cyclohexanes has been carried out. The nature of the HAT reagent, C-H bond strengths, and torsional effects are important determinants of site-selectivity, with the latter effects that play a major role in the reactions of oxygen-centered HAT reagents with monosubstituted cyclohexanes.

To Rebound or...Rebound? Evidence for the "alternative Rebound" mechanism in Ca'H Oxidations by the systems nonheme Mn Complex/H2O2/carboxylic acid

Ottenbacher, Roman V.,Bryliakova, Anna A.,Shashkov, Mikhail V.,Talsi, Evgenii P.,Bryliakov, Konstantin P.

, p. 5517 - 5524 (2021/05/31)

In this work, it has been shown that aliphatic Ca'H oxidations by bioinspired catalyst systems Mn aminopyridine complex/H2O2/carboxylic acid in acetonitrile afford predominantly a mixture of the corresponding alcohol and the ester. The trends governing the alcohol/ester ratios have been rationalized in terms of steric properties of the catalyst, acid, and substrate. copy; 2021 American Chemical Society.

1462-03-9 Process route

cyclopentylmethylamine
6053-81-2

cyclopentylmethylamine

cis-nitrous acid
7782-77-6

cis-nitrous acid

1-amino-cyclopentanemethanol
3637-61-4

1-amino-cyclopentanemethanol

1-methylcyclopentanol
1462-03-9

1-methylcyclopentanol

cyclohexanol
108-93-0

cyclohexanol

Conditions
Conditions Yield
 
  
cis-2-methylcyclopentyl phenyl sulfoxide

cis-2-methylcyclopentyl phenyl sulfoxide

acetonitrile
75-05-8,26809-02-9

acetonitrile

S-Phenyl benzenethiosulfonate
1212-08-4

S-Phenyl benzenethiosulfonate

trans-2-methylcyclopentanol

trans-2-methylcyclopentanol

1-methylcyclopentanol
1462-03-9

1-methylcyclopentanol

S-phenyl benzenethiosulfinate
1208-20-4,6930-77-4,133670-27-6

S-phenyl benzenethiosulfinate

N-1-methylcyclopentane-acetamide
39192-25-1

N-1-methylcyclopentane-acetamide

diphenyldisulfane
882-33-7

diphenyldisulfane

Conditions
Conditions Yield
With titanium(IV) oxide; silver sulfate; In water; at 20 ℃; for 0.5h; Irradiation;
27.3%
0.8%
5.5%

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