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590-67-0

  • Product Name11 -Methylcyclohexanol
  • Molecular FormulaC7H14O
  • Molecular Weight114.19
  • Purity99%
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  • CasNo： 590-67-0
  • Molecular Formula： C7H14O
  • Purity： 99%

Export High Quality 1-Methylcyclohexanol 590-67-0

  • Molecular Formula:C7H14O
  • Molecular Weight:114.188
  • Appearance/Colour:clear colorless to light yellow liquid 
  • Melting Point:24-26 °C(lit.) 
  • Refractive Index:n20/D 1.4585(lit.)  
  • Boiling Point:156.999 °C at 760 mmHg 
  • PKA:15.38±0.20(Predicted) 
  • Flash Point:67.778 °C 
  • PSA：20.23000 
  • Density:0.937 g/cm3 
  • LogP:1.70150 

11 -Methylcyclohexanol(Cas 590-67-0) Usage

1-Methylcyclohexanol is a tertiary alcohol and a member of the cyclohexanols class, characterized by a straw-colored liquid appearance and a weak coconut odor. It is produced through a direct hydration process, which is notable for its energy efficiency and economic feasibility. This chemical compound is used as a raw material for various industrial chemicals and serves as a solvent in the manufacturing of textiles, silk, and soap. Additionally, 1-Methylcyclohexanol is listed as a hazardous substance by OSHA and is recognized by organizations such as ACGIH, DOT, NIOSH, and NFPA.

InChI:InChI=1/C7H14O/c1-7(8)5-3-2-4-6-7/h8H,2-6H2,1H3

590-67-0 Relevant articles

Applications of Pyridine-Containing Polymers in Organic Chemistry

Gerald L. Goe, Charles R. Marston, Eric F. V. Scriven, Edward E. Sowers

Catalysis of Organic Reactions

They have been tested in the acetylation of 1-methylcyclohexanol and the rearrangement of (1) to (2). Yields of products obtained in these reactions using our polymer-supported DMAP …

Products of ozone oxidation of some saturated cyclic hydrocarbons

Khalitova,Grabovskiy,Antipin,Spirikhin,Kabal'Nova

, p. 1710 - 1716 (2015)

Low-temperature ozone oxidation of a ser...

Cyclic molecules: Configuration and conformation

Dipak K. Mandal

Stereochemistry and Organic Reactions, 2021

1,1-Disubstituted cyclohexanes can exist in two interconvertible conformers if the substituents are different. Consider the case of 1-methylcyclohexanol (Fig. 3.22A). Since Me has higher A value than OH, the preferred conformer is expected to be (e-Me, a-OH) conformer, which has indeed been observed in DMSO (major:minor = 7:3).

Deciphering Reactivity and Selectivity Patterns in Aliphatic C-H Bond Oxygenation of Cyclopentane and Cyclohexane Derivatives

Martin, Teo,Galeotti, Marco,Salamone, Michela,Liu, Fengjiao,Yu, Yanmin,Duan, Meng,Houk,Bietti, Massimo

supporting information, p. 9925 - 9937 (2021/06/30)

A kinetic, product, and computational st...

590-67-0 Process route

1,2-epoxy-1-methylcyclohexane
1713-33-3

1,2-epoxy-1-methylcyclohexane

1-Methylcyclohexanol
590-67-0

1-Methylcyclohexanol

1-Phenylethanol
98-85-1,13323-81-4

1-Phenylethanol

Conditions
Conditions Yield
With sodium aluminum tetrahydride; In tetrahydrofuran; at 0 ℃; for 24h; Yield given. Yields of byproduct given;
 
methyl cyclohexane
82166-21-0

methyl cyclohexane

1-Methylcyclohexanol
590-67-0

1-Methylcyclohexanol

cyclohexylmethyl alcohol
100-49-2

cyclohexylmethyl alcohol

Conditions
Conditions Yield
With air; dihydrogen peroxide; olefin carbonyl osmium(0); In acetonitrile; at 60 ℃; Further Variations:; Catalysts; Reagents; Temperatures; Product distribution;
 
With oxalic acid; Mn2(IV) complex with 1,4,7-trimethyl-1,4,7-triazacyclononane; In acetonitrile; at 50 ℃;
 
methyl cyclohexane; With aluminum(III) nitrate nonahydrate; dihydrogen peroxide; In water; acetonitrile; at 70 ℃;
With triphenylphosphine; In water; acetonitrile;
 
methyl cyclohexane; With sodium metavanadate tetrahydrate; sulfuric acid; dihydrogen peroxide; In water; acetonitrile; at 50 ℃;
With triphenylphosphine; In water; acetonitrile;
 
methyl cyclohexane; With 2-pyrazylcarboxylic acid; [{VO(EtO)(EtOH)}2(1κ2O,κN:2κ2O,κN-bis(2-hydroxybenzylidene)oxalohydrazonic acid)]·2H2O; dihydrogen peroxide; In water; acetonitrile; at 50 ℃;
With triphenylphosphine;
 
With pyridine; C16H26CuN5O5(1+)*NO3(1-); dihydrogen peroxide; In acetonitrile; for 1h; Reagent/catalyst; Overall yield = 15.2 %Chromat.;
 
methyl cyclohexane; With [VOCl2(bis[N-(2,6-diisopropylphenyl)imino]acenaphthene)]; dihydrogen peroxide; In water; acetonitrile;
With triphenylphosphine; In water; acetonitrile; Reagent/catalyst; regioselective reaction;
 
With C12H8N2*C13H7NO4(2-)*Cu(2+)*H2O; dihydrogen peroxide; In acetonitrile; at 50 ℃; for 2h; under 760.051 Torr; Reagent/catalyst;
 

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