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Product Details
Chemical Properties |
Tan solid |
Uses |
suzuki reaction |
Purification Methods |
Crystallise the boronic acid from dilute HCl (m 180-184o). The disodium salt has m 209-213o. [Beilstein 16 IV 1679.] |
InChI:InChI=1/C14H11BO2/c16-15(17)14-12-7-3-1-5-10(12)9-11-6-2-4-8-13(11)14/h1-9,16-17H
New blue emitting materials based on dua...
New asymmetric biaryls have been synthes...
(Chemical Equation Presented) The synthe...
Owing to the difficulty in comprehensive...
The Ullmann coupling has been used exten...
A new dual core derivative of 1-(3,5-dip...
The solid state structures of a number o...
Polymer light-emitting diodes (PLEDs) ha...
New green emitting compounds based on tr...
The present invention relates to: an ele...
PURPOSE: A phenanthridine derivative com...
The present invention is directed to a s...
triethyl borate
9-Bromoanthracene
anthracene-9-boronic acid
Conditions | Yield |
---|---|
9-Bromoanthracene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h;
triethyl borate; In tetrahydrofuran; at -78 ℃;
|
90% |
9-Bromoanthracene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h;
triethyl borate; In tetrahydrofuran;
With hydrogenchloride; In tetrahydrofuran; water;
|
89% |
9-Bromoanthracene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h;
triethyl borate; In tetrahydrofuran;
|
89% |
9-Bromoanthracene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h;
triethyl borate; In tetrahydrofuran; at -78 ℃; Further stages.;
|
72.1% |
With n-butyllithium; In tetrahydrofuran;
|
62.4% |
With n-butyllithium; In tetrahydrofuran;
|
9-Bromoanthracene
anthracene-9-boronic acid
Conditions | Yield |
---|---|
9-Bromoanthracene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h;
With triethyl borate; In tetrahydrofuran;
|
85% |
9-Bromoanthracene; With n-butyllithium; In tetrahydrofuran; hexane; toluene; at -40 - -10 ℃; for 0.5h;
With Trimethyl borate; In tetrahydrofuran; hexane; toluene; at -70 - 20 ℃;
With hydrogenchloride; In tetrahydrofuran; hexane; water; toluene;
|
73% |
9-Bromoanthracene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h;
With triethyl borate; In tetrahydrofuran;
With hydrogenchloride; water; In tetrahydrofuran;
|
72.1% |
9-Bromoanthracene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 2h; Inert atmosphere;
With Triisopropyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃;
|
66.2% |
9-Bromoanthracene; With n-butyllithium; In diethyl ether; hexane; at 20 ℃; for 3h;
With Triisopropyl borate; In diethyl ether; hexane; at 0 - 20 ℃;
With hydrogenchloride; In diethyl ether; hexane; for 4h; Further stages.; cooling;
|
63% |
9-Bromoanthracene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.25h;
With Trimethyl borate; In tetrahydrofuran; hexane; at -78 - 25 ℃; for 0.5h;
|
|
9-Bromoanthracene; With n-butyllithium; In tetrahydrofuran; for 1h; cooling;
With Trimethyl borate; In tetrahydrofuran; for 2h; cooling;
With hydrogenchloride; In tetrahydrofuran; water;
|
|
Multi-step reaction with 2 steps
1.1: n-BuLi / tetrahydrofuran; hexane / -78 - 0 °C
1.2: tetrahydrofuran; hexane / 0.33 h / 0 °C
2.1: HCl; H2O / tetrahydrofuran; hexane
With hydrogenchloride; n-butyllithium; water; In tetrahydrofuran; hexane; 1.1: Metallation / 1.2: Substitution / 2.1: Hydrolysis;
|
|
9-Bromoanthracene; With sec.-butyllithium; In diethyl ether; at 0 - 20 ℃; for 1h;
With Triisopropyl borate; at 20 ℃; for 18h;
With hydrogenchloride; methanol; water; sodium hydrogencarbonate; more than 3 stages;
|
|
In ethyl acetate;
|
|
Multi-step reaction with 2 steps
1.1: n-butyllithium / tetrahydrofuran; hexane / -78 °C
1.2: -78 - 20 °C
2.1: water; hydrogenchloride / tetrahydrofuran; hexane / 20 °C / pH 3 - 5
With hydrogenchloride; n-butyllithium; water; In tetrahydrofuran; hexane;
|
|
With n-butyllithium; triethyl borate; In tetrahydrofuran;
|
di-[9]anthryl-hydroxy-borane
9-anthracenylboronic acid dimethyl ester
9-Bromoanthracene
triethyl borate
4,4'-bis(9-anthryl)biphenyl
4-(9'-anthryl)-4-iodobiphenyl
2-anthracen-9-yl-5-hydroxymethyl-benzene-1,3-diol
9-(4-bromomethyl-2,6-bis-hexyloxy-phenyl)-anthracene
CAS:1001911-63-2
Molecular Formula:C<sub>18</sub> H<sub>14</sub> BNO<sub>2</sub>
Molecular Weight:287.1
CAS:610-09-3
Molecular Formula:C<sub>8</sub>H<sub>12</sub>O<sub>4</sub>
Molecular Weight:172.18