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Product Details
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Description |
3-Bromo-9,9-dimethylfluorene is an aromatic hydrocarbon derivative and can be used as an intermediate in organic synthesis. |
| Uses | 1. Intermediate: As an important intermediate in chemical synthesis, it may be used to prepare other compounds or materials. 2. OLED intermediate: As an intermediate of organic light-emitting diodes (OLED), it plays an important role in the synthesis of optoelectronic materials. |
Isomeric SMILES: CC1(C2=C(C=C(C=C2)Br)C3=CC=CC=C31)C
InChIKey: VECLPBKDHAALGQ-UHFFFAOYSA-N
InChI: InChI=1S/C15H13Br/c1-15(2)13-6-4-3-5-11(13)12-9-10(16)7-8-14(12)15/h3-9H,1-2H3
The invention provides a heat activation...
The invention discloses a compound conta...
The present invention relates to an orga...
3‐bromo‐9H‐fluorene
methyl iodide
3‐bromo‐9,9‐dimethyl‐9H‐fluorene
| Conditions | Yield |
|---|---|
|
With sodium t-butanolate; In dimethyl sulfoxide; at 80 - 90 ℃; for 0.5h;
|
96% |
|
With sodium t-butanolate; In dimethyl sulfoxide; at 20 - 65 ℃; for 1h;
|
95% |
|
With sodium t-butanolate; In tetrahydrofuran; for 6h; Inert atmosphere;
|
85.3% |
|
With potassium tert-butylate; In dimethyl sulfoxide; at 80 - 90 ℃;
|
65 mmol |
|
With potassium tert-butylate; In dimethyl sulfoxide; at 80 - 90 ℃; for 0.5h;
|
30 g |
methyl 5-bromo-[1,1'-biphenyl]-2-carboxylate
methylmagnesium bromide
3‐bromo‐9,9‐dimethyl‐9H‐fluorene
| Conditions | Yield |
|---|---|
|
methyl 5-bromo-[1,1'-biphenyl]-2-carboxylate; methylmagnesium bromide; In tetrahydrofuran; at 0 - 20 ℃; for 3h; Inert atmosphere;
With hydrogenchloride; acetic acid; In water; for 10h; Reflux;
|
86% |
3‐bromo‐9H‐fluorene
methyl iodide
methyl 4-bromo-2-iodobenzoate
phenylboronic acid
CAS:28320-31-2
Molecular Formula:C<sub>15</sub>H<sub>13</sub>Br
Molecular Weight:273.17
CAS:92343-46-9
Molecular Formula:C<sub>8</sub>H<sub>10</sub>O<sub>3</sub>
Molecular Weight:154.16
CAS:100622-34-2
Molecular Formula:C<sub>14</sub>H<sub>11</sub>BO<sub>2</sub>
Molecular Weight:222.05
