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Product Details
Description |
2,2'-bithiophene is an intermediate widely used for the synthesis of small molecules or polymer semiconductors in application of organic electronics.?It has proven that?2,2'-bithiophene exists as a mixture of the cis-like and the trans-like planar structures. 5,5'-positions of?2,2'-bithiophene are easily accessible for bromination and stannylation to give 5,5'-dibromo-2,2'-bithiophene or 5,5'-trimethylstannyl-2,2'-bithiophene, which can be used for direct arylation reactions. |
Chemical Properties |
white to light yellow crystal powder |
Uses |
2,2’Bithiophene is a reactant in the preparation of thienophenyl compounds. |
Definition |
ChEBI: A thiophene derivative that consists of two thiophene rings connected by a 2,2'-linkage. |
Synthesis Reference(s) |
The Journal of Organic Chemistry, 51, p. 2627, 1986 DOI: 10.1021/jo00364a002Synthetic Communications, 19, p. 307, 1989 DOI: 10.1080/00397918908050983 |
General Description |
2,2′-Bithiophene is an electron transporting material with the π-electrons present in the system that facilitate charge mobility. |
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thiophene
thiophene-2-carbonitrile
2,2'-Bithiophene
Conditions | Yield |
---|---|
With aluminium trichloride; ethanedinitrile;
|
2,3-dibromothiophen
thiophen-2-yl magnesium bromide
3,3'-bithiophene
2,2'-Bithiophene
3-bromo-[2,2’]bithiophenyl
2,2':3',2-terthiophene
Conditions | Yield |
---|---|
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In diethyl ether; at 0 ℃; for 3h;
|
7% 82% |
thiophene
bis(2-thiophenecarbonyl) peroxide
2-bromothiophene
2-Iodothiophene
2-([2,2']bithienyl-5-carbonyl)-benzoic acid
5,5'-di(1-oxoethyl)-2,2'-bithiophene
2,2'-bithiophene-5-carboxaldehyde
5,5'-diiodo-2,2-bithiophene
CAS:15155-41-6
Molecular Formula:C6H2Br2N2S
Molecular Weight:293.97
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