492-97-7

  • Product Name2,2'-Bithiophene
  • Molecular FormulaC8H6S2
  • Molecular Weight166.3
  • Purity99%
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Product Details

Quick Details

  • CasNo: 492-97-7
  • Molecular Formula: C8H6S2
  • Purity: 99%

High Quality 2,2'-Bithiophene 492-97-7 Good Supplier

  • Molecular Formula:C8H6S2
  • Molecular Weight:166.268
  • Appearance/Colour:white to light yellow crystal powder 
  • Melting Point:32-33 °C(lit.) 
  • Refractive Index:1.6210 (estimate) 
  • Boiling Point:259.999 °C at 760 mmHg 
  • Flash Point:76.261 °C 
  • PSA:56.48000 
  • Density:1.244 g/cm3 
  • LogP:3.47660 

2,2'-Bithiophene(Cas 492-97-7) Usage

Description

2,2'-bithiophene is an intermediate widely used for the synthesis of small molecules or polymer semiconductors in application of organic electronics.?It has proven that?2,2'-bithiophene exists as a mixture of the cis-like and the trans-like planar structures. 5,5'-positions of?2,2'-bithiophene are easily accessible for bromination and stannylation to give 5,5'-dibromo-2,2'-bithiophene or 5,5'-trimethylstannyl-2,2'-bithiophene, which can be used for direct arylation reactions.

Chemical Properties

white to light yellow crystal powder

Uses

2,2’Bithiophene is a reactant in the preparation of thienophenyl compounds.

Definition

ChEBI: A thiophene derivative that consists of two thiophene rings connected by a 2,2'-linkage.

Synthesis Reference(s)

The Journal of Organic Chemistry, 51, p. 2627, 1986 DOI: 10.1021/jo00364a002Synthetic Communications, 19, p. 307, 1989 DOI: 10.1080/00397918908050983

General Description

2,2′-Bithiophene is an electron transporting material with the π-electrons present in the system that facilitate charge mobility.

 

492-97-7 Relevant articles

Desorption/ionization on self-assembled monolayer surfaces (DIAMS)

Sanguinet,Aleveque,Blanchard,Dias,Levillain,Rondeau

, p. 830 - 833 (2006)

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Solution processable alternating oligothiophene-PEO-block-copolymers: Synthesis and evidence for solvent dependent aggregation

Kilbinger,Feast

, p. 1777 - 1784 (2000)

A new route to oligothiophene-PEO-block-...

Receptor- And ligand-based study on novel 2,2′-bithienyl derivatives as non-peptidic AANAT inhibitors

Lepailleur, Alban,Lemaitre, Stephane,Feng, Xiao,Santos, Jana Sopkova-De Oliveira,Delagrange, Philippe,Boutin, Jean,Renard, Pierre,Bureau, Ronard,Rault, Sylvain

, p. 446 - 460 (2010)

Arylalkylamine N-acetyl transferase (ser...

492-97-7 Process route

thiophene
188290-36-0,8014-23-1,25233-34-5

thiophene

thiophene-2-carbonitrile
1003-31-2

thiophene-2-carbonitrile

2,2'-Bithiophene
492-97-7

2,2'-Bithiophene

Conditions
Conditions Yield
With aluminium trichloride; ethanedinitrile;
 
2,3-dibromothiophen
3140-93-0

2,3-dibromothiophen

thiophen-2-yl magnesium bromide
5713-61-1

thiophen-2-yl magnesium bromide

3,3'-bithiophene
3172-56-3

3,3'-bithiophene

2,2'-Bithiophene
492-97-7

2,2'-Bithiophene

3-bromo-[2,2’]bithiophenyl
19690-69-8

3-bromo-[2,2’]bithiophenyl

2,2':3',2-terthiophene
105124-96-7

2,2':3',2-terthiophene

Conditions
Conditions Yield
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In diethyl ether; at 0 ℃; for 3h;
7%
82%

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