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Product Details
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Chemical Properties |
off-white to beige crystalline powder |
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Uses |
suzuki reaction |
InChI:InChI=1/C6H6BClO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H
The reaction of borane complexes with ar...
The invention relates to the technical f...
The invention belongs to the technical f...
Despite recent advancements in metal-cat...
The invention belongs to the technical f...
bromochlorobenzene
Trimethyl borate
4-Chlorophenylboronic acid
4-Bromophenylboronic acid
| Conditions | Yield |
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bromochlorobenzene; With magnesium; In tetrahydrofuran; at 66 ℃; Inert atmosphere;
Trimethyl borate; In tetrahydrofuran; at -20 - -10 ℃; for 6h;
With hydrogenchloride; In water; Overall yield = 26.67 g;
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bromochlorobenzene
4-Chlorophenylboronic acid
| Conditions | Yield |
|---|---|
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bromochlorobenzene; With n-butyllithium; In tetrahydrofuran; hexane; Inert atmosphere;
With Trimethyl borate; In tetrahydrofuran; hexane; Inert atmosphere;
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90% |
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bromochlorobenzene; With diisobutylaluminium hydride; magnesium; lithium chloride; In tetrahydrofuran; toluene; at 20 ℃; for 0.166667h; Inert atmosphere;
With Trimethyl borate; In tetrahydrofuran; toluene; at 0 ℃; Inert atmosphere;
With hydrogenchloride; water; In tetrahydrofuran; toluene; at 0 ℃; Inert atmosphere;
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81% |
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bromochlorobenzene; With tert.-butyl lithium; In tetrahydrofuran; at -78 ℃;
With Trimethyl borate; In tetrahydrofuran; at -78 - 20 ℃; Further stages.;
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74% |
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bromochlorobenzene; With n-butyllithium; In tetrahydrofuran; hexane; toluene; at -70 ℃; for 1.5h;
With Triisopropyl borate; In tetrahydrofuran; hexane; toluene; at -70 - -20 ℃; Further stages.;
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75 % Chromat. |
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bromochlorobenzene; With n-butyllithium; In tetrahydrofuran; hexane; toluene; at -78 ℃; for 1h; Inert atmosphere;
With Triisopropyl borate; In tetrahydrofuran; hexane; toluene; at -78 ℃; for 1h;
With hydrogenchloride; water; In tetrahydrofuran; hexane; toluene; at -20 - 110 ℃;
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bromochlorobenzene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 3h;
With Trimethyl borate; In tetrahydrofuran; at -78 - 20 ℃;
With hydrogenchloride; In tetrahydrofuran; water; for 1h;
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Multi-step reaction with 2 steps
1.1: n-butyllithium / tetrahydrofuran; pentane / 0.06 h / -65 °C / Inert atmosphere
1.2: 0.1 h / -65 °C / Inert atmosphere
2.1: hydrogenchloride; water / Inert atmosphere
With hydrogenchloride; n-butyllithium; water; In tetrahydrofuran; pentane;
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Multi-step reaction with 2 steps
1.1: n-butyllithium / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere; Schlenk technique
1.2: -78 - 20 °C / Inert atmosphere; Schlenk technique
2.1: hydrogenchloride / water / 20 °C / Inert atmosphere; Schlenk technique
With hydrogenchloride; n-butyllithium; In tetrahydrofuran; water;
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bromochlorobenzene; With magnesium; In tetrahydrofuran; at 20 ℃; for 3h;
With Trimethyl borate; In tetrahydrofuran; at -78 - 20 ℃;
In toluene; for 1h; Reflux; Dean-Stark;
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bromochlorobenzene; With n-butyllithium; Triisopropyl borate; In tetrahydrofuran; hexane; toluene; at -78 - -20 ℃; Inert atmosphere;
With hydrogenchloride; In tetrahydrofuran; hexane; water; toluene; at 10 ℃;
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Multi-step reaction with 2 steps
1: magnesium; iodine / toluene; tetrahydrofuran / 2.5 h / 40 - 50 °C / Inert atmosphere
2: hydrogenchloride / 3 h / 20 - 30 °C / pH 2 - 3
With hydrogenchloride; iodine; magnesium; In tetrahydrofuran; toluene;
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Multi-step reaction with 2 steps
1: magnesium; iodine / toluene; tetrahydrofuran / 2.5 h / 40 - 50 °C / Inert atmosphere
2: hydrogenchloride / 3 h / 20 - 30 °C / pH 2 - 3
With hydrogenchloride; iodine; magnesium; In tetrahydrofuran; toluene;
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di-(p-chlorophenyl)borinic acid
(4-chlorphenyl)magnesium bromide
1-Chloro-4-iodobenzene
bromochlorobenzene
diethyl 4-chlorophenylboronate
tris(4-chlorophenyl)boroxine
2-(4-chloro-phenyl)-2,3-dihydro-1H-benzo[1,3,2]diazaborole
5-bromo-2-(4-chloro-phenyl)-5-nitro-[1,3,2]dioxaborinane
CAS:145965-14-6
