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Product Details
|
Chemical Properties |
off-white powder |
| DSSTox Substance ID | DTXSID60735801 |
| Wikidata | Q72443825 |
InChI=1S/C27H23N/c1-27(2)24-14-8-6-13-22(24)23-17-16-20(18-25(23)27)28-26-15-9-7-12-21(26)19-10-4-3-5-11-19/h3-18,28H,1-2H3
The invention discloses a tetraphenyl et...
The invention relates to the technical f...
The invention belongs to the technical f...
Disclosed is a novel compound containing...
2-bromo-9,9-dimethyl-9H-fluorene
2-phenylaniline
N‐{[1,1'‐biphenyl]‐2‐yl}‐9,9‐dimethylfluoren‐2‐amine
| Conditions | Yield |
|---|---|
|
With 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; sodium t-butanolate; In toluene; for 20h; Reflux; Inert atmosphere;
|
95% |
|
With 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; sodium t-butanolate; In toluene; for 20h; Reflux;
|
95% |
|
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate; In toluene; at 110 ℃; for 12h;
|
94% |
|
With copper(l) iodide; potassium carbonate; In 1,4-dioxane; at 100 ℃; for 12h; Inert atmosphere;
|
91% |
|
2-bromo-9,9-dimethyl-9H-fluorene; 2-phenylaniline; With sodium t-butanolate; for 0.25h; Inert atmosphere;
With tri-tert-butyl phosphine; In toluene; at 95 ℃; for 1h;
|
76% |
|
With tris-(dibenzylideneacetone)dipalladium(0); triphenylphosphine; sodium t-butanolate; In toluene; at 105 ℃; for 24h; Inert atmosphere;
|
75.9% |
|
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate; In toluene; at 115 ℃; for 24h; Inert atmosphere;
|
65.9% |
|
With tri-tert-butyl phosphine; potassium tert-butylate; palladium diacetate; In toluene; for 2h; Inert atmosphere; Reflux;
|
61% |
|
With tri-(tert-butyl) phosphate; potassium tert-butylate; palladium diacetate; In toluene; for 4h; Inert atmosphere; Reflux;
|
61% |
|
With tri-tert-butyl phosphine; potassium tert-butylate; palladium diacetate; In toluene; for 4h; Inert atmosphere; Reflux;
|
61% |
|
With tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; XPhos; In toluene; for 5h; Inert atmosphere; Reflux;
|
60% |
|
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate; In toluene; for 2h; Reflux;
|
46.2 g |
|
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium t-butanolate; In toluene; at 90 ℃; for 5h; Inert atmosphere;
|
9,9-dimethyl-9H-fluoren-2-ylamine
2-Bromobiphenyl
N‐{[1,1'‐biphenyl]‐2‐yl}‐9,9‐dimethylfluoren‐2‐amine
| Conditions | Yield |
|---|---|
|
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium t-butanolate; In toluene; at 100 ℃; for 12h;
|
87% |
|
With 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; sodium t-butanolate; In toluene; at 80 ℃; for 12h; Inert atmosphere;
|
83% |
|
With 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; sodium t-butanolate; In toluene; at 80 ℃; for 12h; Inert atmosphere;
|
83% |
|
With tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; XPhos; In toluene; at 105 - 110 ℃; for 4h; Inert atmosphere;
|
80% |
|
With tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; XPhos; In toluene; at 105 - 110 ℃; for 2h; Inert atmosphere;
|
71% |
2-bromo-9,9-dimethyl-9H-fluorene
2-phenylaniline
2-iodo-9,9-dimethyl-9H-fluorene
9,9-dimethyl-9H-fluoren-2-ylamine
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CAS:1001911-63-2
Molecular Formula:C<sub>18</sub> H<sub>14</sub> BNO<sub>2</sub>
Molecular Weight:287.1
CAS:393841-81-1
Molecular Formula:C33H31Br
Molecular Weight:507.5
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