14647-23-5

Product Name1,2-Bis(diphenylphosphino)ethane nickel(ii) chloride
Molecular FormulaC26H24Cl2NiP2
Molecular Weight528
Purity99%

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CasNo： 14647-23-5
Molecular Formula： C26H24Cl2NiP2
Purity： 99%

High Purity [1,2-Bis(diphenylphosphino)ethane]dichloronickel 14647-23-5 On Sale

Molecular Formula:C26H24Cl2NiP2
Molecular Weight:528.02
Appearance/Colour:Orange to red crystalline powder
Vapor Pressure:3.38E-10mmHg at 25°C
Melting Point:263-265 °C(lit.)
Boiling Point:514.8 °C at 760 mmHg
Flash Point:281.7 °C
PSA：27.18000
LogP:-0.73980

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride(Cas 14647-23-5) Usage

Chemical Properties	Orange to red crystalline powder
Uses	suzuki reaction

InChI:InChI=1/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2

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14647-23-5 Process route

: 31387-22-1
dimethylnickel{1,2-bis(diphenylphosphino)ethane}

: 14647-23-5
1,2-bis(diphenylphosphino)ethane nickel(II) chloride

: 74-84-0
ethane

: 88544-62-1
NiPh(Cl)(1,2-bis(diphenylphosphino)ethane)

: 88544-61-0
NiCl(Me)(1,2-bis(diphenylphosphino)ethane)

: 108-88-3,15644-74-3,16713-13-6
toluene

Conditions

Conditions	Yield
With chlorobenzene; In neat (no solvent); mixt. of educt and PhCl stirred at room temp. for 5 d; hexane added, ppt. dissolved in THF, solid recovered by addn. of hexane; GLC, NMR anal.;	55% 50% 14%

: 31387-22-1
dimethylnickel{1,2-bis(diphenylphosphino)ethane}

: 79-03-8
propionyl chloride

: 14647-23-5
1,2-bis(diphenylphosphino)ethane nickel(II) chloride

: 34557-54-5,27936-85-2
methane

: 74-84-0
ethane

: 74-85-1
ethene

: 67-64-1
acetone

Conditions

Conditions	Yield
In toluene; toluene and EtCOCl added to Ni complex at -196°C, after evacuation stirred at room temp. for 24 h; ppt. collected by filtration, crystd. from THF-Et2O; GLC anal.;	88% 51% 21% 15% 8%