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85-42-7

  • Product NameHexahydrophthalic anhydride
  • Molecular FormulaC8H10O3
  • Purity99%
  • AppearanceColorless and clear viscous liquid
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Product Details

Quick Details

  • CasNo: 85-42-7
  • Molecular Formula: C8H10O3
  • Appearance: Colorless and clear viscous liquid
  • Purity: 99%

Hot Sale, Good Manufacturer Offer High Quality Purity 99% Industrial Grade Hexahydrophthalic anhydride 85-42-7 Specifications with Best Price

  • Molecular Formula:C8H10O3
  • Molecular Weight:154.166
  • Appearance/Colour:Colorless and clear viscous liquid 
  • Vapor Pressure:0.003mmHg at 25°C 
  • Melting Point:32-34 °C(lit.) 
  • Refractive Index:1.502 
  • Boiling Point:283.351 °C at 760 mmHg 
  • PKA:4.14[at 20 ℃] 
  • Flash Point:143.909 °C 
  • PSA:43.37000 
  • Density:1.236 g/cm3 
  • LogP:0.87620 

Hexahydrophthalic anhydride(Cas 85-42-7) Usage

Description

Hexahydrophthalic anhydride (HHPA) is a versatile compound with diverse applications, ranging from its fundamental role as a hardener in epoxy resin systems to its use in the synthesis of various chemical compounds. Its resistance to yellowing makes it particularly valuable in casting and coating applications where maintaining color stability is essential.

Chemical Properties

Appears as a white crystalline powder. Can also exist as a clear liquid.

Uses

Epoxy Resin Hardener:

Primarily used as a hardener in epoxy resin systems.
Intermediate for Various Compounds:

Used as an intermediate for coating resins (alkyds, polyesters).
Employed in the synthesis of plasticizers, sealants, and rust inhibitors.
Insect Repellents:

Used in the production of insect repellents.
Electronics Applications:

Widely used in electronics applications for cured epoxy resins with excellent dielectric properties and high-temperature stability.
Resistance to Yellowing:

Preferred in casting and coating applications for its higher resistance to yellowing.

Definition

ChEBI: A cyclic dicarboxylic anhydride that is the cyclic anhydride of hexahydrophthalic acid.

Allergenicity Classified as a highly allergenic compound.
XLogP3-AA 1.2
Complexity 187

Flammability and Explosibility

Nonflammable

Synthesis

The predominantly cis 1,2-cyclohexanedicarboxylic anhydride is versatile, serving as a plasticizer, rust inhibitor, and curing agent for epoxy-based resins. The synthesis of Hexahydrophthalic anhydride involves reacting ciscyclohexane-1,2-dicarboxylic acid with oxalyl chloride, resulting in a crucial compound with various applications in polymerization, adhesives, and corrosion prevention.

InChI:InChI=1/C8H10O3/c9-7-5-3-1-2-4-6(5)8(10)11-7/h5-6H,1-4H2/t5-,6+

85-42-7 Relevant articles

Alternative Formulations to Potentially Replace the Use of Hexahydrophthalic Anhydride in Coil Coatings

CHRISTOPHER BATCHELOR

, Swansea, Wales, UK 2023

A study was performed to investigate degradation of clear coats exposed to aggressive environments via accelerated and natural weathering and periodically analysed for changes in gloss and colour alongside InfraRed analysis, performed with the drive to potentially replace HHPA (Hexahydrophthalic Anhydride) in future coating systems.

Investigations on the curing of epoxy resins with hexahydrophthalic anhydride

Bettina Steinmann

, Journal of Applied Polymer Science, Volume37, Issue7 March 1989 Pages 1753-1776

The bifunctional epoxides bisphenol A diglycidyl ether (BADGE) and hexahydrophthalic diglycidyl ester (HHDGE) as well as the monoepoxides phenyl glycidyl ether (PGE) and cyclohexane carboxylic acid glycidyl ester (CHGE) were cured with hexahydrophthalic anhydride (HHPA) in the presence of benzyldimethylamine (BDMA) or 1-methylimidazole (1-MI) as catalysts at 100–140°C.

85-42-7 Process route

benzene-1,2-dicarboxylic acid
88-99-3,73607-73-5

benzene-1,2-dicarboxylic acid

2-methyl-1-cyclohexanecarboxylic acid
7077-04-5,10479-51-3,56586-13-1

2-methyl-1-cyclohexanecarboxylic acid

cyclohexane-1,2-dicarboxylic acid
1687-30-5

cyclohexane-1,2-dicarboxylic acid

1,2-Cyclohexanedicarboxylic acid-anhydride
85-42-7

1,2-Cyclohexanedicarboxylic acid-anhydride

Conditions
Conditions Yield
With 5% active carbon-supported ruthenium; hydrogen; In 1,4-dioxane; at 179.84 ℃; for 12h; under 51680.2 Torr;
 
benzene-1,2-dicarboxylic acid
88-99-3,73607-73-5

benzene-1,2-dicarboxylic acid

phthalic anhydride
85-44-9

phthalic anhydride

2-methyl-1-cyclohexanecarboxylic acid
7077-04-5,10479-51-3,56586-13-1

2-methyl-1-cyclohexanecarboxylic acid

1,2-Cyclohexanedicarboxylic acid-anhydride
85-42-7

1,2-Cyclohexanedicarboxylic acid-anhydride

Conditions
Conditions Yield
With 5%-palladium/activated carbon; hydrogen; In 1,4-dioxane; at 219.84 ℃; for 12h; under 51680.2 Torr;
 

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