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1-Bromo-9,9'-Spirobi[9H-fluorene] is a polyfluorene compound characterized by its robust molecular structure, featuring two fluorene molecules connected via carbon atoms in a methylene bridge. This unique arrangement results in two perpendicularly oriented π systems, making it particularly valuable in organic electronics.The synthesis of this compound involves a series of steps starting from 1,3-dibromobenzene, progressing through the preparation of a Grignard reagent, reaction with halogenated benzene and fluorenone, followed by hydrolysis and intramolecular cyclization catalyzed by boron trifluoride. 1-Bromo-9,9'-Spirobi[9H-fluorene] is primarily used in the development of advanced materials for organic solar cells, where it functions as an electron acceptor, contributing to high power conversion efficiencies in bulk heterojunction solar cells. Additionally, it serves in the creation of conjugated microporous polymers for potential gas absorption applications and as a hole transporting material in perovskite solar cells. This compound also finds utility in the synthesis of azo and phthalocyanine dyes, which are extensively used in the textile industry. With a molecular weight of 395.3, it is a solid at room temperature, melting between 212-216°C.
2-Bromobiphenyl
1-bromo-9H-fluoren-9-one
1-bromospiro-9,9′-bifluorene
Conditions | Yield |
---|---|
2-Bromobiphenyl; 1-bromo-9H-fluoren-9-one; With iodine; magnesium; In tetrahydrofuran; monoethylene glycol diethyl ether; 1,2-dichloro-ethane; toluene; at 20 - 50 ℃; for 16h;
With hydrogenchloride; acetic acid; In water; at 40 - 100 ℃; for 2h;
|
68% |
2-Bromobiphenyl; With magnesium; In tetrahydrofuran; 1,2-dimethoxyethane; 1,2-dichloro-ethane; toluene; at 70 ℃;
1-bromo-9H-fluoren-9-one; In tetrahydrofuran; 1,2-dimethoxyethane; 1,2-dichloro-ethane; toluene; at 20 - 50 ℃; for 16h;
With acetic acid; at 40 - 100 ℃; for 2h;
|
68% |
2-Bromobiphenyl; 1-bromo-9H-fluoren-9-one; With magnesium; In tetrahydrofuran; 1,2-dimethoxyethane; 1,2-dichloro-ethane; toluene; at 20 - 70 ℃; for 16h;
With acetic acid; at 40 - 100 ℃; for 2h; Acidic conditions;
|
68% |
C25H17BrO
1-bromospiro-9,9′-bifluorene
Conditions | Yield |
---|---|
With boron trifluoride; In dichloromethane; at -20 ℃; Temperature;
|
220.9 g |
The CAS number of 1-BroMo-9,9'-spirobi[9H-fluorene] is 1450933-18-2.
Synonyms for 1-BroMo-9,9'-spirobi[9H-fluorene] 1450933-18-2:1-BroMo-9,9'-spirobi[9H-fluorene]
The chemical formula of 1-BroMo-9,9'-spirobi[9H-fluorene] is C25H15Br which containing 25 Carbon atoms,15 Hydrogen atoms and 1 Bromine atoms,and the molecular weight of 1-BroMo-9,9'-spirobi[9H-fluorene] is 395.2906.
Puyang Huicheng Electronic Material Co., Ltd is a quality supplier of 1-BroMo-9,9'-spirobi[9H-fluorene]. Our main goal is customer satisfaction. Contact us to negotiate the best price for your business on high purity 1-BroMo-9,9'-spirobi[9H-fluorene] 1450933-18-2.
The invention provides a spirofluorene a...
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The present invention relates to compoun...
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Molecular Formula:C<sub>15</sub>H<sub>13</sub>Br
Molecular Weight:273.17
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Molecular Weight:166.17
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Molecular Weight:419.4