902518-11-0

  • Product NameN-(2-bromophenyl)-9h-carbazole
  • Molecular FormulaC18H12BrN
  • Molecular Weight322.2
  • Purity99%
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Product Details

Quick Details

  • CasNo: 902518-11-0
  • Molecular Formula: C18H12BrN
  • Purity: 99%

Industrial Grade N-(2-BroMophenyl)-9H-carbazole 902518-11-0 Powder

  • Molecular Formula:C18H12BrN
  • Molecular Weight:322.204
  • Melting Point:93-94℃ 
  • Boiling Point:462.0±37.0 °C at 760 mmHg 
  • Flash Point:233.2±26.5 °C 
  • PSA:4.93000 
  • Density:1.4±0.1 g/cm3 
  • LogP:5.54620 

N-(2-BroMophenyl)-9H-carbazole(Cas 902518-11-0) Usage

Uses

9-(2-Bromophenyl)-9H-carbazole is a useful reagent for organic synthesis.

XLogP3-AA 5.7

N-(2-Bromophenyl)carbazole can be used as pharmaceutical intermediates; general reagents; OLED material intermediates; OLED intermediates.

Isomeric SMILES: C1=CC=C2C(=C1)C3=CC=CC=C3N2C4=CC=CC=C4Br  
InChIKey: KEWDVYIULXXMPP-UHFFFAOYSA-N  
InChI: InChI=1S/C18H12BrN/c19-15-9-3-6-12-18(15)20-16-10-4-1-7-13(16)14-8-2-5-11-17(14)20/h1-12H  

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Thiery, Sébastien,Tondelier, Denis,Geffroy, Bernard,Jeannin, Olivier,Rault-Berthelot, Jo?lle,Poriel, Cyril

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902518-11-0 Process route

9H-carbazole
86-74-8,105184-46-1,97960-57-1

9H-carbazole

2,3-dibromobenzene
583-53-9

2,3-dibromobenzene

9-(2-bromophenyl)-9H-carbazole
902518-11-0

9-(2-bromophenyl)-9H-carbazole

Conditions
Conditions Yield
9H-carbazole; 2,3-dibromobenzene; With potassium carbonate; for 0.5h; Inert atmosphere;
With copper(l) iodide; L-lysine; at 163 ℃; for 38h;
83%
With copper(I) oxide; potassium phosphate; N,N-dimethylethylenediamine; In toluene; at 120 ℃;
58%
With copper(I) oxide; potassium phosphate; N,N`-dimethylethylenediamine; In 5,5-dimethyl-1,3-cyclohexadiene; at 130 ℃; for 48h; Inert atmosphere; Schlenk technique;
58%
With copper(I) oxide; potassium phosphate; N,N`-dimethylethylenediamine; In toluene; at 120 ℃; for 72h;
55%
With copper; potassium carbonate; In dimethyl sulfoxide; at 20 ℃; for 20.5h; Inert atmosphere; Reflux;
55%
With copper; potassium carbonate; In dimethyl sulfoxide; at 20 ℃; for 20.5h; Inert atmosphere; Reflux;
55%
With copper; potassium carbonate; In dimethyl sulfoxide; at 20 ℃; for 20.5h; Inert atmosphere; Reflux;
55%
With copper; potassium carbonate; In dimethyl sulfoxide; at 20 ℃; for 20.5h; Inert atmosphere; Reflux;
55%
With copper; potassium carbonate; In dimethyl sulfoxide; at 20 ℃; for 0.5h; Inert atmosphere;
55%
With copper(l) iodide; 18-crown-6 ether; In 1,2-dichloro-benzene; at 100 - 210 ℃; Inert atmosphere; Darkness;
53%
With copper(I) oxide; 1,10-Phenanthroline; potassium carbonate; In N,N-dimethyl-formamide; at 155 ℃; for 24h; Inert atmosphere;
41%
With copper(l) iodide; 1,10-Phenanthroline; potassium hydroxide; In o-xylene; for 8h; Reflux; Inert atmosphere;
39%
With copper(l) iodide; potassium carbonate; In N,N-dimethyl acetamide; at 160 ℃; for 72h; Inert atmosphere; Schlenk technique;
38%
With copper(l) iodide; potassium carbonate; In N,N-dimethyl-formamide;
 
With copper(l) iodide; potassium carbonate; In N,N-dimethyl acetamide; for 24h; Inert atmosphere; Reflux;
 
With copper(l) iodide; potassium carbonate; In N,N-dimethyl acetamide; for 24h; Inert atmosphere; Reflux;
 
1-Bromo-2-iodobenzene
583-55-1

1-Bromo-2-iodobenzene

9H-carbazole
86-74-8,105184-46-1,97960-57-1

9H-carbazole

9-(2-bromophenyl)-9H-carbazole
902518-11-0

9-(2-bromophenyl)-9H-carbazole

Conditions
Conditions Yield
With copper(l) iodide; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; for 12h; Inert atmosphere; Reflux;
85%
With potassium phosphate; copper(l) iodide; N,N`-dimethylethylenediamine; In 5,5-dimethyl-1,3-cyclohexadiene; at 120 ℃; for 48h;
65%
With copper; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; for 48h; Inert atmosphere; Reflux;
56%
With copper(l) iodide; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; for 48h; Inert atmosphere; Reflux;
56%
With copper(l) iodide; potassium carbonate; In N,N-dimethyl-formamide; at 140 ℃; for 48h;
47%
With copper(l) iodide; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; at 120 ℃; for 12h; Inert atmosphere;
45%
With copper(I) oxide; 2,2,6,6-tetramethylheptane-3,5-dione; potassium hydroxide; In N,N-dimethyl-formamide; at 110 ℃; for 24h; Inert atmosphere; Schlenk technique;
41%
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate; In toluene; at 100 ℃; for 20h; Inert atmosphere; Reflux;
29%
With potassium carbonate; copper(l) iodide; In xylene; Heating / reflux;
25%
With potassium carbonate; copper(l) iodide; In xylene; Reflux; Inert atmosphere;
25%
With potassium carbonate; copper(l) iodide; In xylene; Reflux; Inert atmosphere;
25%
With copper(l) iodide; potassium carbonate; In N,N-dimethyl acetamide; at 130 ℃; for 48h; Inert atmosphere;
25%
With copper(l) iodide; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; at 120 ℃;
25.5%
With copper(l) iodide; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; Inert atmosphere; Reflux;
25%
With copper(l) iodide; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; Inert atmosphere; Reflux;
25%
With copper(l) iodide; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; Reflux; Inert atmosphere;
25%
With copper(l) iodide; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; Reflux; Inert atmosphere;
 
With potassium carbonate; copper(II) sulfate; In 1,2-dichloro-benzene;
 

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