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Product Details
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Description |
N-(2-Bromophenyl)-9H-carbazole is an organic compound which is composed of a carbazole unit substituted with a bromine atom at the 2-position of the phenyl ring. N-(2-Bromophenyl)-9H-carbazole is a solid at room temperature and exhibits interesting photophysical and electronic properties. N-(2-Bromophenyl)-9H-carbazole has potential applications in the field of organic electronics, such as in the development of organic light-emitting diodes (OLEDs), organic field-effect transistors (OFETs), and other optoelectronic devices, due to its ability to participate in charge transport and photochemical processes. The presence of the bromine substituent can also provide opportunities for further chemical modifications and functionalization of the molecule. |
| XLogP3-AA | 5.7 |
N-(2-Bromophenyl)carbazole can be used as pharmaceutical intermediates; general reagents; OLED material intermediates; OLED intermediates.
Isomeric SMILES: C1=CC=C2C(=C1)C3=CC=CC=C3N2C4=CC=CC=C4Br
InChIKey: KEWDVYIULXXMPP-UHFFFAOYSA-N
InChI: InChI=1S/C18H12BrN/c19-15-9-3-6-12-18(15)20-16-10-4-1-7-13(16)14-8-2-5-11-17(14)20/h1-12H
This work reports a detailed structure–p...
Herein, we report two simple and efficie...
Two rigid spiro-type TADF emitters (CBZA...
The present invention relates to an orga...
The present invention relates to a compo...
The invention belongs to the technical f...
9H-carbazole
2,3-dibromobenzene
9-(2-bromophenyl)-9H-carbazole
| Conditions | Yield |
|---|---|
|
9H-carbazole; 2,3-dibromobenzene; With potassium carbonate; for 0.5h; Inert atmosphere;
With copper(l) iodide; L-lysine; at 163 ℃; for 38h;
|
83% |
|
With copper(I) oxide; potassium phosphate; N,N-dimethylethylenediamine; In toluene; at 120 ℃;
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58% |
|
With copper(I) oxide; potassium phosphate; N,N`-dimethylethylenediamine; In 5,5-dimethyl-1,3-cyclohexadiene; at 130 ℃; for 48h; Inert atmosphere; Schlenk technique;
|
58% |
|
With copper(I) oxide; potassium phosphate; N,N`-dimethylethylenediamine; In toluene; at 120 ℃; for 72h;
|
55% |
|
With copper; potassium carbonate; In dimethyl sulfoxide; at 20 ℃; for 20.5h; Inert atmosphere; Reflux;
|
55% |
|
With copper; potassium carbonate; In dimethyl sulfoxide; at 20 ℃; for 20.5h; Inert atmosphere; Reflux;
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55% |
|
With copper; potassium carbonate; In dimethyl sulfoxide; at 20 ℃; for 20.5h; Inert atmosphere; Reflux;
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55% |
|
With copper; potassium carbonate; In dimethyl sulfoxide; at 20 ℃; for 20.5h; Inert atmosphere; Reflux;
|
55% |
|
With copper; potassium carbonate; In dimethyl sulfoxide; at 20 ℃; for 0.5h; Inert atmosphere;
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55% |
|
With copper(l) iodide; 18-crown-6 ether; In 1,2-dichloro-benzene; at 100 - 210 ℃; Inert atmosphere; Darkness;
|
53% |
|
With copper(I) oxide; 1,10-Phenanthroline; potassium carbonate; In N,N-dimethyl-formamide; at 155 ℃; for 24h; Inert atmosphere;
|
41% |
|
With copper(l) iodide; 1,10-Phenanthroline; potassium hydroxide; In o-xylene; for 8h; Reflux; Inert atmosphere;
|
39% |
|
With copper(l) iodide; potassium carbonate; In N,N-dimethyl acetamide; at 160 ℃; for 72h; Inert atmosphere; Schlenk technique;
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38% |
|
With copper(l) iodide; potassium carbonate; In N,N-dimethyl-formamide;
|
|
|
With copper(l) iodide; potassium carbonate; In N,N-dimethyl acetamide; for 24h; Inert atmosphere; Reflux;
|
|
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With copper(l) iodide; potassium carbonate; In N,N-dimethyl acetamide; for 24h; Inert atmosphere; Reflux;
|
1-Bromo-2-iodobenzene
9H-carbazole
9-(2-bromophenyl)-9H-carbazole
| Conditions | Yield |
|---|---|
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With copper(l) iodide; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; for 12h; Inert atmosphere; Reflux;
|
85% |
|
With potassium phosphate; copper(l) iodide; N,N`-dimethylethylenediamine; In 5,5-dimethyl-1,3-cyclohexadiene; at 120 ℃; for 48h;
|
65% |
|
With copper; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; for 48h; Inert atmosphere; Reflux;
|
56% |
|
With copper(l) iodide; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; for 48h; Inert atmosphere; Reflux;
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56% |
|
With copper(l) iodide; potassium carbonate; In N,N-dimethyl-formamide; at 140 ℃; for 48h;
|
47% |
|
With copper(l) iodide; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; at 120 ℃; for 12h; Inert atmosphere;
|
45% |
|
With copper(I) oxide; 2,2,6,6-tetramethylheptane-3,5-dione; potassium hydroxide; In N,N-dimethyl-formamide; at 110 ℃; for 24h; Inert atmosphere; Schlenk technique;
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41% |
|
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate; In toluene; at 100 ℃; for 20h; Inert atmosphere; Reflux;
|
29% |
|
With potassium carbonate; copper(l) iodide; In xylene; Heating / reflux;
|
25% |
|
With potassium carbonate; copper(l) iodide; In xylene; Reflux; Inert atmosphere;
|
25% |
|
With potassium carbonate; copper(l) iodide; In xylene; Reflux; Inert atmosphere;
|
25% |
|
With copper(l) iodide; potassium carbonate; In N,N-dimethyl acetamide; at 130 ℃; for 48h; Inert atmosphere;
|
25% |
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With copper(l) iodide; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; at 120 ℃;
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25.5% |
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With copper(l) iodide; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; Inert atmosphere; Reflux;
|
25% |
|
With copper(l) iodide; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; Inert atmosphere; Reflux;
|
25% |
|
With copper(l) iodide; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; Reflux; Inert atmosphere;
|
25% |
|
With copper(l) iodide; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; Reflux; Inert atmosphere;
|
|
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With potassium carbonate; copper(II) sulfate; In 1,2-dichloro-benzene;
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1-Bromo-2-iodobenzene
9H-carbazole
2,3-dibromobenzene
2-bromoaniline
8,8-diphenyl-8H-indolo[3,2,1-de]acridine
8-(4-bromophenyl)-8-phenyl-8H-indolo-[3,2,1-de]acridine
8,8-bis(4-bromophenyl)-8H-indolo-[3,2,1-de]acridine
9-(2-(diethylphosphino)phenyl)-9H-carbazole
CAS:15155-41-6
Molecular Formula:C6H2Br2N2S
Molecular Weight:293.97
CAS:1428551-28-3
Molecular Formula:C24H16BrN
Molecular Weight:398.3
CAS:1028648-22-7
Molecular Formula:C24H18BNO2
Molecular Weight:363.2
