185112-61-2

  • Product NameN-(3-bromophenyl)carbazole,9-(3-bromophenyl)carbazole
  • Molecular FormulaC18H12BrN
  • Molecular Weight322.2
  • Purity99%
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Product Details

Quick Details

  • CasNo: 185112-61-2
  • Molecular Formula: C18H12BrN
  • Purity: 99%

N-(3-Bromophenyl)carbazole 185112-61-2 In Stock with Wholesale Price

  • Molecular Formula:C18H12BrN
  • Molecular Weight:322.204
  • Melting Point:69-70 °C 
  • Boiling Point:462.9±37.0 °C at 760 mmHg 
  • Flash Point:233.7±26.5 °C 
  • PSA:4.93000 
  • Density:1.4±0.1 g/cm3 
  • LogP:5.54620 

9-(3-bromophenyl)carbazole(Cas 185112-61-2) Usage

Chemical Properties

White solid

XLogP3-AA 5.7
Complexity 322

9-(3-Bromophenyl)carbazole can be used in dyes, pigments, and intermediates of synthetic materials.

Isomeric SMILES: C1=CC=C2C(=C1)C3=CC=CC=C3N2C4=CC(=CC=C4)Br  
InChIKey: ZKGHGKNHPPZALY-UHFFFAOYSA-N  
InChI: InChI=1S/C18H12BrN/c19-13-6-5-7-14(12-13)20-17-10-3-1-8-15(17)16-9-2-4-11-18(16)20/h1-12H  

185112-61-2 Relevant articles

Synthesis of pyrimidine-cored host materials bearing phenylcarbazole for efficient yellow phosphorescent devices: Effect of linkage position

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Two isomeric host materials were synthes...

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Efficient orange-red phosphorescent organic light-emitting diodes using an in situ synthesized copper(i) complex as the emitter

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, (2021/04/05)

We have synthesized a series of novel hy...

ORGANIC COMPOUND HAVING IMPROVED LUMINESCENT PROPERTIES, ORGANIC LIGHT EMITTING DIODE AND ORGANIC LIGHT EMITTING DEVICE HAVING THE COMPOUND

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Paragraph 0224; 0225, (2020/07/16)

An organic compound, an organic light em...

Compound, display panel and display device

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Paragraph 0103-0105, (2020/01/12)

The present invention relates to the tec...

Method for synthesizing N-aryl carbazole compound by catalyzing reaction of carbazole with aryl hydrazine by using transition metal

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185112-61-2 Process route

1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

9H-carbazole
86-74-8,105184-46-1,97960-57-1

9H-carbazole

9-(3-bromophenyl)carbazole
185112-61-2

9-(3-bromophenyl)carbazole

Conditions
Conditions Yield
With copper; potassium carbonate; In N,N-dimethyl-formamide; at 130 ℃;
98%
With potassium phosphate; copper(l) iodide; trans-1,2-cyclohexanediamine; In toluene; for 4h;
96%
With palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; In toluene; at 110 ℃;
90%
With copper; potassium carbonate; In N,N-dimethyl-formamide; at 130 ℃; for 24h; Inert atmosphere;
89%
With copper; potassium carbonate; In N,N-dimethyl-formamide; at 130 ℃; for 24h;
89%
With copper(I) oxide; 2,2,6,6-tetramethylheptane-3,5-dione; potassium hydroxide; In N,N-dimethyl-formamide; at 110 ℃; for 24h; Inert atmosphere; Schlenk technique;
84%
With copper; potassium carbonate; at 150 ℃; for 48h; Inert atmosphere;
82.4%
With 18-crown-6 ether; copper; potassium carbonate; In N,N-dimethyl-formamide; at 150 ℃; Inert atmosphere;
79%
With copper; potassium carbonate; In Tetraethylene glycol dimethyl ether; at 140 ℃; for 5h;
78%
With copper(l) iodide; potassium carbonate; In 5,5-dimethyl-1,3-cyclohexadiene; for 48h; Inert atmosphere; Reflux;
78%
With tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate; In toluene; for 3h; Inert atmosphere; Reflux;
77%
With dibenzo-18-crown-6; copper; potassium carbonate; In N,N-dimethyl-formamide; for 7h; Inert atmosphere; Reflux;
71%
With potassium phosphate; copper(l) iodide; In 1,4-dioxane; at 90 ℃; for 12h; Inert atmosphere;
70%
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate; In toluene; at 80 ℃;
70%
With potassium phosphate; copper(II) iodide; rac-diaminocyclohexane; In 1,4-dioxane; for 16h; Inert atmosphere; Reflux;
69%
With copper; potassium carbonate; In N,N-dimethyl-formamide; at 150 ℃; for 48h; Inert atmosphere;
65%
With 18-crown-6 ether; copper; potassium carbonate; In N,N-dimethyl-formamide; for 24h; Sealed tube; Inert atmosphere; Reflux;
64.8%
With copper; potassium carbonate; In N,N-dimethyl-formamide; at 130 ℃; for 24h; Inert atmosphere;
58%
With potassium carbonate; rac-diaminocyclohexane; copper(l) chloride; In dimethyl sulfoxide; at 110 ℃; for 16h; Inert atmosphere;
46%
With copper(l) iodide; 18-crown-6 ether; potassium carbonate; In N,N-dimethyl-formamide; at 130 ℃; for 24h;
36%
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate; In toluene; at 100 ℃; for 16h; Inert atmosphere; Reflux;
35%
With sodium t-butanolate; 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium(0); In xylene; for 24h; Inert atmosphere; Reflux;
 
With copper; potassium carbonate; In N,N-dimethyl-formamide;
 
With Cu-catalyst; In dichlorobenzene;
 
With dibenzo-18-crown-6; copper; potassium carbonate; In 1,2-dichloro-benzene; at 100 ℃; for 12h; Inert atmosphere;
 
With copper; potassium carbonate; In N,N-dimethyl-formamide; at 130 ℃;
 
With potassium carbonate; In 1,2-dichloro-benzene;
 
With copper(l) iodide; Reflux;
 
1-Bromo-3-iodobenzene; With tri-tert-butyl phosphine; palladium diacetate; In toluene; at 20 ℃; for 1h; Inert atmosphere;
9H-carbazole; In toluene; at 80 ℃; for 6h; Inert atmosphere;
1.9 g
With copper(l) iodide; (-)-(1R,2R)-diaminocyclohexane; Reflux;
 
With dibenzo-18-crown-6; copper; potassium carbonate; In 1,2-dichloro-benzene; at 100 ℃;
 
With potassium phosphate; copper(l) iodide; In 1,4-dioxane; at 90 ℃; for 12h;
 
With potassium phosphate; copper(l) iodide; In 1,4-dioxane; at 90 ℃; for 12h;
 
With copper(l) iodide; potassium carbonate; In N,N-dimethyl-formamide; at 150 ℃; for 12h;
 
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

9H-carbazole
86-74-8,105184-46-1,97960-57-1

9H-carbazole

9-(3-bromophenyl)carbazole
185112-61-2

9-(3-bromophenyl)carbazole

Conditions
Conditions Yield
With potassium phosphate; copper(l) iodide; ethylenediamine; In toluene; at 120 ℃; for 24h;
85%
With copper; potassium carbonate; nitrobenzene; at 120 - 160 ℃; Inert atmosphere;
85%
With copper(l) iodide; potassium carbonate; N,N`-dimethylethylenediamine; In 5,5-dimethyl-1,3-cyclohexadiene; at 120 ℃; for 24h; Inert atmosphere;
83%
With copper; potassium carbonate; In N,N-dimethyl-formamide; at 130 ℃; Inert atmosphere;
71%
 
47%
With copper(l) iodide; potassium carbonate; In N,N-dimethyl-formamide;
 
With copper(l) iodide; calcium carbonate; at 158 ℃; Inert atmosphere;
 
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; potassium tert-butylate; In 5,5-dimethyl-1,3-cyclohexadiene; for 6h; Reflux;
80 mmol

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