136630-39-2

  • Product Name2,7-Dibromo-9h-carbazole
  • Molecular FormulaC12H7Br2N
  • Molecular Weight325
  • Purity99%
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Product Details

Quick Details

  • CasNo: 136630-39-2
  • Molecular Formula: C12H7Br2N
  • Purity: 99%

High Purity 2,7-dibroMocarbazole 136630-39-2 In Stock

  • Molecular Formula:C12H7Br2N
  • Molecular Weight:325.002
  • Vapor Pressure:3.58E-08mmHg at 25°C 
  • Melting Point:230.0 to 234.0 °C 
  • Refractive Index:1.796 
  • Boiling Point:459 °C at 760 mmHg 
  • PKA:15.13±0.30(Predicted) 
  • Flash Point:231.4 °C 
  • PSA:15.79000 
  • Density:1.93 g/cm3 
  • LogP:4.84610 

2,7-Dibromo-9H-carbazole(Cas 136630-39-2) Usage

Application

One of the most popular products made available from 2,7-dibromocarbazole is PCDTBT, a well-known polymer semiconductor used for polymer solar cells. A good example for adjusting the solubility of the carbazole compounds by using 2,7-dibromocarbazole as the starting materials is the synthesis of 2,7-dibromo-9-heptadecanylcarbazole.

Description

2,7-Dibromocarbazole (2,7-DBCZ) is one of the most frequently detected polyhalogenated carbazoles (PHCZs) in the environmental media. 2,7-dibromocarbazole, also known as 2,7-dibromo-9H-carbazole, is a building block for the synthesis of small molecules of carbazole series or carbazole back-boned polymers in the application of OFETs, OLEDs, PLEDs and OPVs.

Chemical Properties

White to light yellow powder or crystals

XLogP3-AA 4.8

Isomeric SMILES: C1=CC2=C(C=C1Br)NC3=C2C=CC(=C3)Br

InChIKey: QPTWWBLGJZWRAV-UHFFFAOYSA-N

InChI:InChI=1/C12H7Br2N/c13-7-1-3-9-10-4-2-8(14)6-12(10)15-11(9)5-7/h1-6,15H

136630-39-2 Relevant articles

Evaluation of the developmental toxicity of 2,7-dibromocarbazole to zebrafish based on transcriptomics assay

Chenyang Ji a, Lu Yan a, Yuanchen Chen a, Siqing Yue a, Qiaoxiang Dong b, Jiangfei Chen b, Meirong Zhao a

, Journal of Hazardous Materials Volume 368, 15 April 2019, Pages 514-522

Polyhalogenated carbazoles (PHCZs), which have the similar structure of dioxin, have been reported ubiquitous in the environments and drawn wide concerns. However, their potential ecological and health risks are still poorly understood. Here, wildtype zebrafish embryos were used to evaluate the environmental risks of 2,7-dibromocarbazole (2,7-DBCZ), 3,6-dibromocarbazole (3,6-DBCZ), and 3,6-dichlorocarbazole (3,6-DCCZ). 2,7-DBCZ was the most toxic compound with the 96-h LC50 value of 581.8 ± 29.3 μg·L−1 and the EC50 value of 201.5 ± 6.5 μg·L−1 for pericardial edema.

Evaluation of the developmental toxicity of 2, 7-dibromocarbazole to zebrafish based on transcriptomics assay

Chenyang Ji , Lu Yan , Yuanchen Chen , Siqing Yue , Qiaoxiang Dong , Jiangfei Chen , Meirong Zhao

Journal of Hazardous Materials Volume 368, 15 April 2019, Pages 514-522

It were used to evaluate the environmental risks of 2,7-dibromocarbazole (2,7-DBCZ), 3,6-dibromocarbazole (3,6-DBCZ), and 3,6-dichlorocarbazole (3,6-DCCZ). 2,7-DBCZ was the most …

Tissue-specific accumulation, depuration and histopathological effects of 3,6-dichlorocarbazole and 2,7-dibromocarbazole in adult zebrafish (Danio rerio)

Mengyao Huang a, Cunchuang Hou a, Qiaoyun Zhang a, Dunfan Yao c, Shengchao Hu a, Guowei Wang a, Shixiang Gao b

, Aquatic Toxicology Volume 266, January 2024, 106803

Here, we investigated the tissue-specific accumulation, depuration, and histopathological effects of two typical PHCZs, 3,6-dichlorocarbazole (36-CCZ) and 2,7-dibromocarbazole (27-BCZ), in adult zebrafish at three levels (0, 0.15 μg/L (5 × environmentally relevant level), and 50 μg/L (1/10 LC50). The lowest concentrations of 36-CCZ (1.2 μg/g ww) and 27-BCZ (1.4 μg/g ww) were observed in muscle, and the greatest concentrations of 36-CCZ (3.6 μg/g ww) and 27-BCZ (4 μg/g ww) were detected in intestine among the tested tissues.

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