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Product Details
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Chemical Properties |
white powder |
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Uses |
2,7-Dibromo-9,9′-spirobifluorene can be used in the preparation of 9,9′-spirobifluorene-based small molecules, which can further be utilized as host materials in organic light emitting diodes (OLEDs). |
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General Description |
2,7-Dibromo-9,9′-spirobifluorene is a 9,9 substituted poly(2,7-fluorene) that is synthesized from 2,7-dribromo-9-fluorenone by reacting with a Grignard reagent of 2-bromobiphenyl. It has high photoluminescence and electroluminescent quantum efficiency that make it useful in the development of organic electronic devices. |
Isomeric SMILES: C1=CC=C2C(=C1)C3=CC=CC=C3C24C5=C(C=CC(=C5)Br)C6=C4C=C(C=C6)Br
InChIKey: UPJLZKCEPFAKSH-UHFFFAOYSA-N
InChI: InChI=1S/C25H14Br2/c26-15-9-11-19-20-12-10-16(27)14-24(20)25(23(19)13-15)21-7-3-1-5-17(21)18-6-2-4-8-22(18)25/h1-14H
The first water-soluble spirobifluorene ...
Porous organic polymers (POPs) with stro...
The invention relates to a method for sy...
2 and visible-light responsive CPs containing 9,9′-spiro-bifluorene and bis(3,4-dimethoxythiophen-2-yl… For example, 2,7-dibromo-9,9′-spiro-bifluorene (95 mg, 0.2 mmol), 4,7-bis (3,4-…
9-((1,1'-biphenyl)-2-yl)-2,7-dibromo-9H-fluoren-9-ol
2,7-dibromo-9,9'-spirobi[fluorene]
| Conditions | Yield |
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hydrogenchloride; In water; acetic acid; for 12h; Heating / reflux;
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89% |
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With hydrogenchloride; acetic acid; In water; at 140 ℃; for 2.5h;
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89% |
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With acetic acid; at 120 ℃; for 24h;
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86% |
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With hydrogenchloride; acetic acid; In water; for 1h; Reflux;
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82% |
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With sulfuric acid; In toluene; at 20 ℃; for 2h;
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80% |
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With hydrogenchloride; In acetic acid; at 50 ℃; Heating / reflux;
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57% |
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With sulfuric acid; for 3h;
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With hydrogenchloride; In acetic acid; Heating;
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10.0 g |
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With hydrogenchloride; for 4h; Product distribution / selectivity; Reflux;
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9-((1,1'-biphenyl)-2-yl)-2,7-dibromo-9H-fluoren-9-ol; With ammonium chloride; at 20 ℃;
With hydrogenchloride; acetic acid; Reflux;
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With acetic acid; Reflux;
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2.84 g |
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With hydrogenchloride; acetic acid; In water; Inert atmosphere; Heating;
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2.83 g |
2,7-dibromofluorene-9-one
phenylmagnesium bromide
2,3-dibromobenzene
2,7-dibromo-9,9'-spirobi[fluorene]
| Conditions | Yield |
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phenylmagnesium bromide; 2,3-dibromobenzene; In 2-methyltetrahydrofuran; at 80 ℃; for 12h; Inert atmosphere;
2,7-dibromofluorene-9-one; In 2-methyltetrahydrofuran; diethyl ether; for 2h; Reflux;
With hydrogenchloride; acetic acid; In 2-methyltetrahydrofuran; diethyl ether; at 75 ℃; for 4h;
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76.2% |
9-((1,1'-biphenyl)-2-yl)-2,7-dibromo-9H-fluoren-9-ol
2,7-dibromofluorene-9-one
2-biphenylmagnesium bromide
2-Bromobiphenyl
2,7-bis (4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9,9′-spirobi[9H-fluorene]
2,7-dicyano-2'-diphenylamino-9,9'-spirobifluorene
2,7-dicyano-2',7'-bis(diphenylamino)-9,9'-spirobifluorene
2,7-dibromo-2',7'-bis(2,2-diphenylvinyl)-9,9'-spirobifluorene
CAS:28320-31-2
Molecular Formula:C<sub>15</sub>H<sub>13</sub>Br
Molecular Weight:273.17
CAS:128055-74-3
Molecular Formula:C25H12Br4
Molecular Weight:632
