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108714-73-4

  • Product Name2-Amino-9,9-dimethylfluorene
  • Molecular FormulaC15H15N
  • Molecular Weight209.29
  • Purity99%
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Product Details

Quick Details

  • CasNo： 108714-73-4
  • Molecular Formula： C15H15N
  • Purity： 99%

Top Purity 2-Amino-9,9-dimethylfluorene 108714-73-4 Powder

  • Molecular Formula:C15H15N
  • Molecular Weight:209.291
  • Vapor Pressure:8.46E-06mmHg at 25°C 
  • Melting Point:166.0 to 170.0 °C 
  • Refractive Index:1.631 
  • Boiling Point:374.2 °C at 760 mmHg 
  • PKA:4.35±0.40(Predicted) 
  • Flash Point:194.3 °C 
  • PSA：26.02000 
  • Density:1.107 g/cm3 
  • LogP:4.15630 

2-Amino-9,9-dimethylfluorene(Cas 108714-73-4) Usage

Chemical Properties

White solid
Uses 2-Amino-9,9-dimethylfluorene can be used as a pharmaceutical intermediate.

Isomeric SMILES: CC1(C2=CC=CC=C2C3=C1C=C(C=C3)N)C

InChIKey: GUTJITRKAMCHSD-UHFFFAOYSA-N

InChI:InChI=1/C15H15N/c1-15(2)13-6-4-3-5-11(13)12-8-7-10(16)9-14(12)15/h3-9H,16H2,1-2H3

108714-73-4 Relevant articles

Photocatalytic C-H Amination of Aromatics Overcoming Redox Potential Limitations

Ikarashi, Gun,Kano, Naokazu,Morofuji, Tatsuya

supporting information, p. 2822 - 2827 (2020/04/16)

We report the photocatalytic C-H aminati...

A review on low-molar-mass carbazole-based derivatives for organic light emitting diodes

G Krucaite, S Grigalevicius

Synthetic Metals, 2019

Carbazole/fluorene-based materials 13c-13d were prepared by the reaction of tetra(tertbutyl)carbazole with 2-bromo-9,9-diphenylfluorene or 2-bromo-9,9′-spirobi[fluorene] [83]. 3,6-…

Approaches to Obtaining Fluorenes: An Alternate Perspective

AS Das, AR Nair, A Sreekumar, A Sivan

ChemistrySelect, 2022

The reaction between n-BuLi and 2-bromo-9,9-diphenylfluorene 92 was conducted at −78 C. Later on, quenching the lithiated compound using dioxaborolane reagent resulted in the …

108714-73-4 Process route

9,9-dimethyl-2-nitro-9H-indole
605644-46-0

9,9-dimethyl-2-nitro-9H-indole

9,9-dimethyl-9H-fluoren-2-ylamine
108714-73-4

9,9-dimethyl-9H-fluoren-2-ylamine

Conditions
Conditions Yield
With calcium chloride; zinc; In ethanol; water; for 6h; Reflux;
89%
With palladium on activated charcoal; hydrazine hydrate; In ethanol; for 4h; Reflux;
88%
With palladium 10% on activated carbon; hydrogen; In ethanol; for 24h;
81%
9,9-dimethyl-2-nitro-9H-indole; With iron(III) chloride hexahydrate; pyrographite; hydrazine hydrate; In methanol; at 90 ℃; for 0.166667h; Reflux; Inert atmosphere;
With hydrazine hydrate; In methanol; at 90 ℃; for 2h; Inert atmosphere;
 
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

9,9-dimethyl-9H-fluoren-2-ylamine
108714-73-4

9,9-dimethyl-9H-fluoren-2-ylamine

Conditions
Conditions Yield
With copper(l) iodide; ammonia; caesium carbonate; In water; N,N-dimethyl-formamide; acetylacetone; at 100 ℃; for 12h;
 
Multi-step reaction with 2 steps
1: potassium phosphate; copper(l) iodide; N,N`-dimethylethylenediamine / xylene / 36 h / 140 °C / Inert atmosphere
2: potassium hydroxide; water / ethanol; xylene / 36 h / Reflux
With potassium phosphate; copper(l) iodide; water; potassium hydroxide; N,N`-dimethylethylenediamine; In ethanol; xylene;
 

108714-73-4 Upstream products

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108714-73-4 Downstream products

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