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144981-85-1

  • Product Name9,9-Dimethyl-2-iodofluorene
  • Molecular FormulaC15H13I
  • Molecular Weight320.17
  • Purity99%
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Product Details

Quick Details

  • CasNo： 144981-85-1
  • Molecular Formula： C15H13I
  • Purity： 99%

Buy Quality 9,9-DiMethyl-2-iodofluorene 144981-85-1, Good Supplier

  • Molecular Formula:C15H13I
  • Molecular Weight:320.173
  • Vapor Pressure:1.56E-05mmHg at 25°C 
  • Melting Point:63-65°C 
  • Refractive Index:1.648 
  • Boiling Point:376.5 °C at 760 mmHg 
  • Flash Point:171 °C 
  • PSA：0.00000 
  • Density:1.533 g/cm3 
  • LogP:4.59750 

9,9-Dimethyl-2-iodofluorene(Cas 144981-85-1) Usage

Chemical Properties

White powder
Canonical SMILES CC1(C2=CC=CC=C2C3=C1C=C(C=C3)I)C
Wikidata Q72483569
Nikkaji Number J446.537G
DSSTox Substance ID DTXSID80452321

InChI:InChI=1/C15H13I/c1-15(2)13-6-4-3-5-11(13)12-8-7-10(16)9-14(12)15/h3-9H,1-2H3

144981-85-1 Relevant articles

A novel class of emitting amorphous molecular materials as bipolar radical formants: 2-{4-[Bis(4-methylphenyl)amino]phenyl}-5-(dimesitylboryl)thiophene and 2-{4-[Bis(9,9-dimethylfluorenyl)amino]phenyl}-5-(dimesitylboryl)thiophene [9]

Shirota,Kinoshita,Noda,Okumoto,Ohara

, p. 11021 - 11022 (2000)

-

Synthesis and dye sensitized solar cell applications of Bodipy derivatives with bis-dimethylfluorenyl amine donor groups

?akmak, Yusuf,Kolemen, Safacan,Buyuktemiz, Muhammed,Dede, Yavuz,Erten-Ela, Sule

, p. 4086 - 4092 (2015)

Three Bodipy dyes with strong absorptivi...

One‐Pot Successive Turbo Grignard Reactions for the Facile Synthesis of α‐Aryl‐α‐Trifluoromethyl Alcohols

Ryunosuke Kani, Dr. Toshiyasu Inuzuka, Dr. Yasuhiro Kubota, Dr. Kazumasa Funabiki

European Journal of Organic Chemistry,Volume2020, Issue29 August 9, 2020 Pages 4487-4493

Fused iodoarenes, such as 2-iodo-9,9-dimethyl-9H-fluorene (1f) and 1-iodonaphthalene (1k), likewise reacted with iPrMgCl·LiCl to give the corresponding α-aryl-α-trifluoromethyl …

Visible-light-driven three-component reductive 1, 2-diarylation of alkenes

T Wang, W Yu, J Lan, H Wang, Z Jiang, Y Li, J Fu

Chem Catalysis, VOLUME 3, ISSUE 5, 100619, MAY 18, 2023

2-iodo-9,9-dimethyl-9H-fluorene (61). Furthermore, a variety of heteroaryl iodides were tested; 2-iodothiophene (62), 4-iodopyridine (63), 2-chloro-4-iodopyridine (64), 2-iodopyrazine (…

144981-85-1 Process route

2-iodo-9H-fluorene
2523-42-4

2-iodo-9H-fluorene

methyl iodide
74-88-4

methyl iodide

2-iodo-9,9-dimethyl-9H-fluorene
144981-85-1

2-iodo-9,9-dimethyl-9H-fluorene

Conditions
Conditions Yield
2-iodo-9H-fluorene; With potassium tert-butylate; In tetrahydrofuran; at 0 ℃; for 0.166667h;
methyl iodide; In tetrahydrofuran; at 0 - 20 ℃;
91%
2-iodo-9H-fluorene; With sodium hydroxide; benzyltrimethylammonium chloride; In water; dimethyl sulfoxide; at 20 ℃; for 3h;
methyl iodide; In water; dimethyl sulfoxide; at 20 ℃; for 3h;
90%
2-iodo-9H-fluorene; With potassium tert-butylate; In tetrahydrofuran; at 20 ℃; for 1.5h;
methyl iodide; In tetrahydrofuran; for 2h;
70%
2-iodo-9H-fluorene; With benzyltrimethylammonium chloride; sodium hydroxide; In water; dimethyl sulfoxide; at 20 ℃; for 3h;
methyl iodide; In water; dimethyl sulfoxide; at 20 ℃; for 3h;
64%
With potassium tert-butylate; In dimethyl sulfoxide; at 0 ℃; for 0.166667h;
 
2-iodo-9H-fluorene; With potassium tert-butylate; In tetrahydrofuran; dimethyl sulfoxide; at 25 ℃; for 0.333333h;
methyl iodide; In tetrahydrofuran; dimethyl sulfoxide; at 25 ℃; for 2.66667h;
 
With potassium tert-butylate; In dimethyl sulfoxide; at 0 ℃; for 0.166667h; Schlenk technique; Inert atmosphere;
 
With potassium methanolate; In N,N-dimethyl-formamide;
 
With sodium methylate; In N,N-dimethyl-formamide; at 20 ℃; for 2h;
21.5 g
2-bromo-9,9-dimethyl-9H-fluorene
28320-31-2

2-bromo-9,9-dimethyl-9H-fluorene

2-iodo-9,9-dimethyl-9H-fluorene
144981-85-1

2-iodo-9,9-dimethyl-9H-fluorene

Conditions
Conditions Yield
2-bromo-9,9-dimethyl-9H-fluorene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 24.5h; Inert atmosphere;
With iodine; In tetrahydrofuran; at -78 - 20 ℃; for 12h; Inert atmosphere;
89%
2-bromo-9,9-dimethyl-9H-fluorene; With n-butyllithium; In tetrahydrofuran; at -78 - 20 ℃; for 24h; Inert atmosphere;
With iodine; In tetrahydrofuran; at -78 - 20 ℃; for 12h; Inert atmosphere;
89%
2-bromo-9,9-dimethyl-9H-fluorene; With n-butyllithium; In tetrahydrofuran; at -78 - 20 ℃; for 24h; Inert atmosphere;
With iodine; In tetrahydrofuran; at -78 - 20 ℃; for 12h; Inert atmosphere;
89%

144981-85-1 Upstream products

  • 2523-42-4
    2523-42-4

    2-iodo-9H-fluorene

  • 74-88-4
    74-88-4

    methyl iodide

  • 28320-31-2
    28320-31-2

    2-bromo-9,9-dimethyl-9H-fluorene

144981-85-1 Downstream products

  • 165320-27-4
    165320-27-4

    9,9-dimethyl-N-(9,9-dimethyl-9H-fluoren-2-yl)-N-phenyl-9H-fluoren-2-amine

  • 333432-28-3
    333432-28-3

    9,9-dimethyl-9H-fluoren-2-yl-2-boronic acid

  • 313050-71-4
    313050-71-4

    N-(4-bromophenyl)-N-(9,9-dimethyl-9H-fluoren-2-yl)-9,9-dimethyl-9H-fluoren-2-amine

  • 940893-14-1
    940893-14-1

    3-(N,N-bis(9,9-dimethylfluoren-2-yl)amino)anisole

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